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Copolymer, dispersant, and dispersion composition

A technology of copolymers and dispersants, applied in the field of copolymers, to achieve the effect of improving dispersion and slump retention

Inactive Publication Date: 2020-04-24
DAI ICHI KOGYO SEIYAKU CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, none of the copolymers described in Patent Document 1 and Patent Document 2 can sufficiently satisfy dispersibility and slump retention.

Method used

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  • Copolymer, dispersant, and dispersion composition
  • Copolymer, dispersant, and dispersion composition
  • Copolymer, dispersant, and dispersion composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~ Embodiment 14, comparative example 1~ comparative example 4

[0141]120 g of ion-exchanged water was poured into a glass reactor equipped with a thermometer, a stirrer, a dropping funnel, a cooling pipe, and a nitrogen introduction pipe, and the inside of the reactor was replaced with nitrogen while stirring, and then the temperature was raised to 80°C. A mixture of 200 g of monomers and 100 g of water and a mixture of 4 g of ammonium persulfate and 80 g of water mixed in the ratio shown in Table 1 were simultaneously added dropwise to the reactor maintained at 80° C. over 2 hours. After completion of the dropwise addition, it was further kept at 80° C. for 2 hours. Then, it was cooled to 40° C., and neutralized to a pH of 7.0 to 7.5 using 24% aqueous sodium hydroxide solution, thereby obtaining Examples 1 to 14 and Comparative Examples having Mw and Mw / Mn shown in Table 1, respectively. The aqueous solution of the copolymer of Example 1-Comparative Example 4.

[0142] Regarding the monomers in Table 1, A-1 to A-5 and B-1 to B-5 are the...

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Abstract

Provided is a copolymer which is able to be used as a dispersant that has excellent dispersibility and excellent slump retention ability. A copolymer according to one embodiment of the present invention is a water-soluble copolymer which contains, as constituent monomers, at least one monomer selected from among monomers (A) represented by formula (1) and monomers (B) represented by formula (2) and at least one monomer (C) selected from among unsaturated carboxylic acid monomers (C-1) and oxyethylene group-containing unsaturated carboxylic acid esters (C-2), and which is configured such that the content of the monomer (C) is from 20% by mass to 99% by mass (inclusive).

Description

technical field [0001] Embodiments of the present invention relate to a copolymer, a dispersant containing the copolymer, and a dispersion composition using the dispersant. Background technique [0002] In order to improve the strength and durability of concrete (concrete), it is effective to reduce the unit amount of water in concrete. However, it is known that if the unit amount of water is reduced, the fluidity of concrete is lowered, which impairs workability. [0003] Therefore, a dispersant for dispersing cement or the like has been studied as a method of improving workability when reducing the unit water amount. For example, Patent Document 1 discloses one obtained by copolymerizing at least three polyoxyalkyl ester-based monomers of unsaturated carboxylic acids and unsaturated monocarboxylic acid-based monomers. In addition, Patent Document 2 discloses a copolymer of an unsaturated polyalkylene glycol alkenyl ether monomer, an unsaturated carboxylic acid monomer, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F290/06C04B24/26C04B24/32C08F299/02C08L33/00C04B103/40
CPCC08F290/06C08F299/02C08L33/00C08F220/06C04B24/2694C04B2103/408C04B2103/308C08F216/125C08F216/1433C08F220/286C08F220/1818C08F220/1807C08F220/36C04B24/2641C08F222/102C04B24/2664C04B24/2676C04B24/32C04B2103/0054C08F212/36C08F220/32
Inventor 城籔将虎盐原启小笠原亚沙子木村拓郎陶颀高町祐辉
Owner DAI ICHI KOGYO SEIYAKU CO LTD