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Precipitation-resistant, scratch-resistant, high-performance and low-cost polypropylene composite material and preparation method thereof

A composite material and polypropylene technology, which is applied in the preparation of scratch-resistant high-performance and low-cost polypropylene composite materials, and in the field of anti-precipitation, can solve the problems of inability to prevent the migration of organic light stabilizers, expensive polytetrafluoroethylene, large precipitation, The risk of stickiness and other issues can be improved to achieve the effect of improving scratch resistance, improving emission performance, and reducing friction coefficient

Pending Publication Date: 2020-05-01
SHANGHAI PRET COMPOSITES +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Application number: CN110317407A discloses a PP composite material with low friction coefficient and its preparation method. The method improves the scratch resistance of the material by adding polytetrafluoroethylene and polysiloxane, but polytetrafluoroethylene is expensive And not easy to fuse with polypropylene matrix
CN102108152A discloses a polypropylene composition with both low emission and excellent light aging resistance. The method can partially or completely replace traditional organic light stabilizers by adding ultrafine titanium dioxide capable of effectively absorbing and shielding ultraviolet rays, thereby obtaining Polypropylene composition with low emission performance and excellent light aging resistance. Although the addition of silicon dioxide can reduce the amount of organic light stabilizer, it cannot prevent the organic light stabilizer from migrating to the surface of polypropylene
For some materials, when using a light stabilizer with a low melting point or using a large amount of light stabilizer, there will be a greater risk of precipitation and stickiness

Method used

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  • Precipitation-resistant, scratch-resistant, high-performance and low-cost polypropylene composite material and preparation method thereof
  • Precipitation-resistant, scratch-resistant, high-performance and low-cost polypropylene composite material and preparation method thereof
  • Precipitation-resistant, scratch-resistant, high-performance and low-cost polypropylene composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~5 and comparative example 1、2

[0036] Weigh the components shown in Examples 1 to 5 and Comparative Examples 1 and 2 in Table 1 by weight percentage: polypropylene, elastomer, inorganic filler, fumed silica, organic light stabilizer, antioxidant, coupling agents, other additives. After these components are uniformly mixed by a high-speed mixer, they are added into a twin-screw extruder, and melted and extruded through the twin-screw extruder.

[0037] Performance evaluation methods and implementation standards

[0038] The dry particles obtained by granulating according to the methods of Examples 1-5 and Comparative Examples 1 and 2 were injection-molded with an injection molding machine to prepare samples.

[0039] The anti-light aging performance is carried out according to the PV1303 standard, the photoperiod is 5 cycles, and the sample size is 145*45*3.2; the scratch resistance test is carried out according to the German Volkswagen PV3952 standard, and the sample size is 50* 50*3.2mm, the load is 10N,...

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Abstract

The invention discloses a precipitation-resistant, scratch-resistant, high-performance and low-cost polypropylene composite material and a preparation method thereof. The modified polypropylene composite material comprises the following components in percentages by weight: 40-90% of polypropylene, 5-15% of an elastomer, 0-30% of an inorganic filling material, 1-15% of fumed silica, 0.05-5% of an organic light stabilizer, 0.1-1.5% of an antioxidant, 0-2% of a coupling agent and 0-2% of auxiliary agents. According to the invention, the fumed silica has an extremely strong ultraviolet absorptionfunction, so the usage amount of the light organic stabilizer is reduced; and the fumed silica particles generate hydrogen-bond interaction through silanol groups existing on the surfaces of the fumedsilica particles to form an aggregate network, and the silanol groups and the aggregate network structure have effective adsorption and migration inhibition effects on the organic light stabilizer, so migration of the organic light stabilizer to the surface of a product is reduced. Meanwhile, the fumed silica has an excellent lubricating effect, so the friction coefficient of the surface of the product can be effectively reduced, and the usage amount of a scratch-resistant auxiliary agent can be reduced.

Description

technical field [0001] The invention relates to a high-performance and low-cost polypropylene composite material resistant to precipitation and scratching; the invention also provides a preparation method of the high-performance and low-cost polypropylene composite material resistant to precipitation and scratching. Background technique [0002] With the continuous development of the automobile industry, lightweight, safety, comfort, and aesthetics have become the focus of attention. Due to its excellent performance, low price and easy processing and molding, polypropylene is widely used in the automotive field, such as dashboards, sub-dashboards, door panels, pillars, bumpers, etc. As people's aesthetic requirements for automotive interiors are getting higher and higher, OEMs' performance requirements for materials are also constantly improving. The air quality in the car is the focus of major OEMs, so reducing the use of additives is beneficial to improve the odor and VOC...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L53/00C08L23/16C08L23/08C08K13/02C08K3/36C08K3/34
CPCC08L23/12C08L53/00C08K2201/006C08L23/16C08L23/0815C08K13/02C08K3/36C08K3/34C08K3/346
Inventor 徐超张锴巩祥壮王溢吴俊蔡青周文
Owner SHANGHAI PRET COMPOSITES