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A special material for high-performance radiation-resistant polypropylene and its preparation method

A technology of irradiated polypropylene and special materials, which is applied in the field of high-performance radiation-resistant polypropylene special materials and its preparation, can solve the problem of not meeting the high requirements for the application performance of medical devices, affecting the safe use of medical devices, and not being scratch-resistant during storage and transportation It can achieve the effects of easy operation and large-scale production, good overall performance, and improved light transmittance and stamping resistance.

Active Publication Date: 2022-03-25
河南驼人医疗器械研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, although the above-mentioned medical radiation-resistant polypropylene material has improved the radiation resistance and impact resistance of the material to a certain extent, the impact resistance of the modified material is still limited, and a variety of small molecules need to be added to the raw materials. Additives, so that small molecules are prone to precipitation after irradiation, which seriously affects the safe use of medical devices
In addition, most of the currently reported medical radiation-resistant polypropylene materials still have problems such as low transparency and scratch resistance during storage and transportation, which are increasingly unable to meet the application performance of high-demand medical devices such as humidification bottles.

Method used

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  • A special material for high-performance radiation-resistant polypropylene and its preparation method
  • A special material for high-performance radiation-resistant polypropylene and its preparation method
  • A special material for high-performance radiation-resistant polypropylene and its preparation method

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preparation example Construction

[0050] The modified masterbills added to the present invention are better compatible with the matrix resin, and each component is synergistic, so that the resulting product has higher impact resistance, good radiation resistance, light transmissive performance and scratch resistance performance. The material of the present invention is higher, and other auxiliaries such as transparent and nucleating agents are not needed to add other auxiliaries such as transparers and nucleating agents. Performance loss and small molecules after irradiation. Embodiments of the present invention also provide a method of preparing a high-performance resistant tolerance polypropylene, including the following steps:

[0051] (1) Advertising the raw material of the modified masterbatch according to the weight of the parts, and the high-speed mixer is mixed, and then the twin screw extruder is used for melting, extrusion, granulation, drying, modified masterbatch;

[0052] (2) Prepare transparent polyp...

Embodiment 1

[0059] A high-performance gas resistant to polypropylene special material is prepared from raw material including the following weight:

[0060] Transparent polypropylene 100 parts;

[0061] 10 copies of PoE;

[0062] 10 copies of modified masterbatch.

[0063] Among them, the modified masterbatch is measured by weight, and the raw material groups are:

[0064]

[0065]

[0066] Preparation method of high performance radiation-resistant polypropylene, including the following steps:

[0067] (1) Advertising the raw material of the modified masterbatch according to the weight of the parts, and the high-speed mixer of the rotation speed is 800r / min, and then invested for a long diameter ratio of 40: 1, the twin screw of the rotation speed is 90R / min. In the discharge, the temperature of the feed section is 120 ° C, the melt segment temperature is 150 ° C, the delivery section is 170 ° C for melt, extrusion, granulation, and finally dried at a temperature of 80 ° C for 5 h, re...

Embodiment 2

[0070] The present embodiment is substantially identical to the first embodiment, and the difference is that a high-performance reflective polypropylene special material is prepared from raw materials including the following weight:

[0071] Transparent polypropylene 100 parts;

[0072] 10 copies of PoE;

[0073] 5 copies of modified masterbatch.

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Abstract

The invention belongs to the technical field of medical material preparation, and discloses a high-performance radiation-resistant polypropylene special material and a preparation method thereof. The polypropylene special material is prepared from the following raw materials by weight: 100 parts of transparent polypropylene, 8-15 parts of polyolefin elastomer, 5-10 parts of modified masterbatch; the modified masterbatch is made of highly transparent Polypropylene, compatibilizer, antioxidant, composite light stabilizer and lubricant are mixed and granulated according to the mass ratio of 85:15:2:3:2. The polypropylene special material has higher impact resistance, good radiation resistance, light transmission and scratch resistance. After electron beam irradiation, its comprehensive performance remains good. At the same time, the types of small molecule additives and The amount of addition is small, which effectively reduces the loss of mechanical properties of the material and the precipitation of small molecules after irradiation, and can better meet the needs of high-performance applications; while the product is prepared by two-time extrusion granulation, the process is simple, the cost is low, and the continuity is strong. The components in the system have good compatibility.

Description

Technical field [0001] The present invention belongs to the technical field of medical materials, and more particularly to a special material for high performance by radiation polypropylene and a preparation method thereof. Background technique [0002] Polypropylene is an important plastic material, which has a wide range of advantages, excellent cost, and excellent performance, has been widely used in the field of medical devices. However, with the continuous development of medical technology, people are increasingly attaching importance to the quality and safety of medical devices, and medical devices usually need to be sterilized before leaving. At present, the commonly used sterilization mainly includes ethylene oxide sterilization and electron beam irradiation sterilization, wherein the electron beam irradiation is sterilized due to non-pollution, no residual, period short, simple operation, and is gradually become a mainstream sterilization. . However, the traditional poly...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/14C08L23/08C08L51/06C08L53/02C08K5/00C08K5/20C08K5/526C08J3/22
CPCC08J3/226C08J2323/14C08J2423/14C08J2423/08C08J2451/06C08J2453/02C08K5/00C08K5/20C08K5/526C08K2201/014
Inventor 郭胜立赵庆彦马玉涵史利利魏莹刘帅李菲王国锋
Owner 河南驼人医疗器械研究院有限公司
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