Metalloporphyrin/agarose freshness indicating label and preparation method thereof
A technology of metalloporphyrin and agarose, which is applied in the direction of material analysis by observing the influence of chemical indicators, and analysis by making materials undergo chemical reactions, can solve the problem of poor film-forming performance, poor accuracy, and sensitivity of porphyrin molecules. Low-level problems, to achieve the effect of simple and novel preparation method, good film-forming performance, and high sensitivity of acid-base detection
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[0029] The present invention also provides a method for preparing a metalloporphyrin / agarose freshness indicator label, comprising the following steps:
[0030] 1) Add agarose into pure water, heat and stir until completely dissolved, and obtain a colorless and transparent agarose gel-like liquid with a concentration of 5g / L-20g / L;
[0031] 2) Add metalloporphyrin chromogen and plasticizer to the agarose jelly liquid prepared in step 1), ultrasonically treat at 45°C-80°C until mixed evenly, then add hydrochloric acid to adjust the pH value to 5 ~6, to obtain a green and transparent mixed solution;
[0032] 3) Put the mixture obtained above in a petri dish, dry at a temperature of 20°C to 60°C for 12h to 48h, and obtain the metal (4-sodium sulfonate) phenylporphyrin / agarose freshness indicator label after cooling , the depth of the petri dish used is 5-20 mm, and the metalloporphyrin / agarose freshness indicator label with a thickness of 1-4 mm is formed after the mixed solutio...
Embodiment 1
[0037]Take 1.86g of agarose and add it to 200mL of pure water, heat and stir until completely dissolved to obtain a transparent agarose jelly liquid with a concentration of 9.3g / L; -sodium sulfonate) phenyl cobalt porphyrin and 0.1mL plasticizer-glycerin (about 0.13g) were added to the above-mentioned agarose jelly liquid, ultrasonically treated at 50°C until uniformly mixed, and then a small amount of 0.1 mol / L~1mol / L hydrochloric acid to adjust the pH value to 6 to obtain a green and transparent mixed solution; take some of the above mixed solution and place it in a petri dish with a depth of 10mm, and cure it at 60°C for 24 hours to obtain a thickness Tetrakis(4-sodiumsulfonate)phenylcobalt porphyrin / agarose freshness indicator label about 1mm.
[0038] The specific preparation process of Examples 2~7, Comparative Example 1 and Comparative Example 2 are as follows with the different conditions of Example 1, and others are the same, as shown in the following table:
[0039]...
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