Method for separating positive electrode active material and current collector of waste lithium battery

A technology for positive electrode active material and waste lithium battery, which is applied in the field of separation of waste lithium battery positive electrode active material and current collector, can solve the problems of increased recycling cost, difficulty in recycling aluminum foil, large and strong alkali, etc., and achieves rapid separation and complete recycling of aluminum foil. , the effect of simplifying the separation process

Inactive Publication Date: 2020-06-23
有研资源环境技术研究院(北京)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method is relatively easy to operate but consumes a large amount of strong alkali, and

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Disassemble the waste lithium battery after discharging, take out the positive electrode sheet, and clean the positive electrode sheet; put the positive electrode sheet into a 5mol / L strong alkali solution and soak it for 3 minutes, and the surface of the aluminum foil current collector will quickly dissolve in the alkali solution and A large number of small hydrogen bubbles are generated. The corrosion of the aluminum foil and the blowing of a large number of bubbles destroy the interface between the aluminum foil and the positive electrode active material, and the two are completely separated under the washing of the water jet; The upper part of the solution is filtered and taken out with a sieve, and the surface of the aluminum foil is cleaned and dried to realize recovery; the positive electrode active material is filtered, cleaned and dried at the bottom of the lye to meet the subsequent recovery process, and the filtered lye continues to be recycled. The positive e...

Embodiment 2

[0027] Disassemble the waste lithium battery after discharging, take out the positive electrode piece, and clean the positive electrode piece; put the positive electrode piece into 20mol / L strong alkali solution and fully soak it for 0.5min, and the surface of the aluminum foil current collector will quickly dissolve in the alkali solution And produce a large number of small hydrogen bubbles, the dissolution of the aluminum foil and the blowing of a large number of bubbles destroy the interface between the aluminum foil and the positive electrode active material, and the two are completely separated under the action of mechanical stirring; stop stirring after separation, and the aluminum foil is in the air bubbles attached to it. Driven to float on the upper part of the solution, after being taken out by sieve filtration, the surface of the aluminum foil is cleaned and dried to realize recovery; the positive electrode active material can be used for subsequent recycling after fi...

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Abstract

The invention discloses a method for separating a positive electrode active material and a current collector of a waste lithium battery. The method comprises the steps of (1) disassembling the waste lithium battery after discharging, taking out a positive plate, and cleaning the positive plate; (2) putting the cleaned positive plate into a high-concentration strong alkali solution to be fully soaked so as to enable an aluminum foil to be basically separated from the positive electrode active material; (3) increasing mechanical stirring or water flow washing effect to promote complete separation of the positive electrode active material and the aluminum foil current collector, sinking the positive electrode active material into the bottom of the solution, and floating the aluminum foil current collector on the solution; and (4) filtering the aluminum foil floating on the upper part of the solution by using a large-mesh screen, washing with clear water, collecting the aluminum foil, collecting the reacted solution to obtain the positive electrode active material, and recycling the alkali liquor. The method provided by the invention can realize rapid separation of the positive electrode active material and the aluminum foil, and reduces the whole recovery cost while simplifying the separation process.

Description

technical field [0001] The invention relates to a method for separating positive electrode active materials and current collectors of waste lithium batteries, and belongs to the technical field of battery recycling. Background technique [0002] Lithium-ion batteries have the advantages of high energy density, long life, low self-discharge rate, no memory effect, good cycle performance, and wide operating temperature range. They are widely used in portable electronic devices such as mobile phones, mobile power supplies, and notebooks. Especially in recent years, the strong demand for lithium-ion batteries used in the field of power batteries has made the production and consumption of lithium-ion batteries reach an unprecedented scale. [0003] The mass production and consumption of lithium-ion batteries lead to the retirement or scrapping of a large number of lithium-ion batteries in the market every year. With the urgent need for environmental protection and clean energy i...

Claims

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Application Information

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IPC IPC(8): H01M10/54
CPCH01M10/54Y02W30/84
Inventor 徐政纪仲光黄孝振杨丽梅
Owner 有研资源环境技术研究院(北京)有限公司
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