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A life-accelerated prediction method for lithium-ion batteries based on low-temperature cycling

A lithium-ion battery, lithium iron phosphate battery technology, applied in secondary batteries, circuits, measuring electricity and other directions, can solve the problems of electrical performance attenuation, flatulence, inapplicability, etc., to accelerate battery attenuation, the method is simple and safe, and the operation is convenient Effect

Active Publication Date: 2022-04-05
SHANGHAI INST OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Especially when the battery works at a temperature lower than 10°C or higher than 60°C, the cycle life begins to decline gradually
Most of the existing technologies use high-temperature cycles for detection. However, due to the increase in the viscosity of the electrolyte at low temperatures, the diffusion coefficient and electrochemical reactivity of lithium ions and electrons are reduced, resulting in significant attenuation of electrical properties; while at high temperatures, the coefficient increases. The attenuation is mainly due to the obvious high-temperature side reactions, and the high-temperature cycle is likely to cause flatulence and cause safety problems, which cannot accelerate the prediction of battery life; in addition, due to the inconsistency of each battery, the high-temperature cycle method cannot be applied to all lithium-ion batteries and lithium ion capacitor

Method used

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  • A life-accelerated prediction method for lithium-ion batteries based on low-temperature cycling
  • A life-accelerated prediction method for lithium-ion batteries based on low-temperature cycling
  • A life-accelerated prediction method for lithium-ion batteries based on low-temperature cycling

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Embodiment

[0031] Cyclic charging and discharging at room temperature will generate lithium dendrites and a small amount of gas production on the surface of the negative electrode with the attenuation of performance. At high temperature, the main side reaction is gas production, and at low temperature, the main side reaction is lithium dendrite generation. In addition, due to the increase of electrolyte viscosity at low temperature, the diffusion coefficient and electrochemical reactivity of lithium ions and electrons are reduced, resulting in significant attenuation of electrical properties; at high temperature, the coefficient increases, and the attenuation is mainly due to the obvious side reactions at high temperature. Therefore, from the analysis of the above mechanism, the attenuation at low temperature is closer to the attenuation at room temperature.

[0032] At normal temperature, as the number of cycles increases in lithium-ion batteries, more lithium cannot be extracted inside...

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Abstract

The invention relates to a life-accelerated prediction method of lithium-ion batteries based on low-temperature cycles. The method makes full use of the characteristics of severe attenuation of lithium-ion batteries at low temperatures, and attenuates the lithium-ion batteries to a specified SOC at low temperatures, and then returns to normal temperature. Cycle, and after three cycles, the discharge capacity is still higher than 80% SOC. The numerical relationship between the number of cycles at low temperature and the number of cycles attenuated to 80% SOC at room temperature can be determined to determine the performance of lithium-ion batteries at different temperatures and at different rates. Methods of life assessment. Compared with the prior art, the present invention has the advantages of universality, simplicity and safety, convenient operation, rich application scenarios and the like.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a method for accelerating the life prediction of lithium-ion batteries based on low-temperature cycles. Background technique [0002] In recent years, lithium-ion batteries, as the main power system of electric vehicles, have been rapidly popularized due to their unique advantages such as long service life, low self-discharge rate, high power density, high energy density, and no pollution. Although lithium-ion batteries have obvious advantages, they have gradually replaced traditional power batteries such as lead-acid batteries and are used in power batteries for electric vehicles. However, for the evaluation of the long life of lithium-ion batteries, it is impossible to rely on conventional testing methods to reduce them to SOC (State of charge, that is, state of charge) is less than 80% of the number of cycles to evaluate life. [0003] Experimental studies have shown that t...

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01R31/392H01M10/0525
CPCG01R31/392H01M10/0525Y02E60/10
Inventor 张全生樊亚平闵凡奇
Owner SHANGHAI INST OF TECH