Environment-friendly flexible matte polyester film for door plate and preparation method thereof
A polyester film, an environmentally friendly technology, applied in the field of environmentally friendly flexible matte polyester film for door panels and its preparation, can solve the problems of insufficient adhesion fastness, whitening of edges and corners, etc., and achieve scratch-resistant appearance effect and good appearance effect Effect
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Embodiment 1
[0026] The flexible matt polyester film for the door panel described in embodiment 1 is prepared according to the following steps:
[0027] 1). The crystalline PET homopolymer, the PET copolymer modified with 1,4-cyclohexanedimethanol and 1,4-butanediol are mixed as the core material according to the mass ratio of 20%:80%. Pre-crystallization and drying treatment until the moisture content is below 100ppm, melting at 260-280°C, extruding with a single-screw extruder, and the extruded molten polymer passes through a pre-filter with a precision of 60 microns, a metering pump with a precision of 25 micron main filter, into the die;
[0028] Wherein, the preparation method of the PET copolymer modified with 1,4-cyclohexanedimethanol and 1,4-butanediol (melting point 235 degrees, intrinsic viscosity 0.8) is as follows: terephthalic acid, ethyl alcohol Diol, 1,4 cyclohexane glycol, 1,4-butanediol in mass ratio 55:15:10:20, carry out esterification reaction at pressure 0.1-0.15MPa, ...
Embodiment 2
[0037] The flexible matt polyester film for the door panel described in embodiment 2 is prepared according to the following steps:
[0038] 1). The crystalline PET homopolymer, the PET copolymer modified with 1,4-cyclohexanedimethanol and 1,4-butanediol are mixed as the core material according to the mass ratio of 20%:80%. Pre-crystallization and drying treatment until the moisture content is below 100ppm, melting at 260-280°C, extruding with a single-screw extruder, and the extruded molten polymer passes through a pre-filter with a precision of 60 microns, a metering pump, a precision 25 micron main filter, enters the die;
[0039] 2). Mix crystalline PET homopolymer (melting point 260 degrees, intrinsic viscosity 0.66) and micron inorganic modified crystalline PET copolymer (melting point 260 degrees, intrinsic viscosity 0.66) according to mass percentage 70%: 30% , as the raw material of the upper surface layer, after pre-crystallization and drying treatment to a moisture ...
Embodiment 3
[0047] The flexible matte polyester film for the door panel described in embodiment 3 is prepared according to the following steps:
[0048] 1). The crystalline PET homopolymer, the PET copolymer modified with 1,4-cyclohexanedimethanol and 1,4-butanediol are mixed as the core material according to the mass ratio of 20%:80%. Pre-crystallization and drying treatment until the moisture content is below 100ppm, melting at 260-280°C, extruding with a single-screw extruder, and the extruded molten polymer passes through a pre-filter with a precision of 60 microns, a metering pump, a precision 25 micron main filter, enters the die;
[0049] 2). Mix crystalline PET homopolymer (melting point 260 degrees, intrinsic viscosity 0.66) and crystalline PET copolymer modified by micron inorganic substances (melting point 260 degrees, intrinsic viscosity 0.66) according to mass percentage 75%: 25% , as the raw material of the upper surface layer, after pre-crystallization and drying treatment...
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