Rubber composition for tire and pneumatic tire
A rubber composition and a technology for pneumatic tires, which are applied in the field of rubber compositions for tires and pneumatic tires, can solve the problem of reduced reinforcement of the rubber composition, deterioration of block-cutting resistance and block-drop resistance, difficulty in taking into account performance, etc. problems, to achieve the effects of low fuel consumption, improved cutting resistance, and improved overall performance
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[0126] The present invention is specifically described based on examples, but the present invention is not limited to these examples.
[0127] Next, various chemical reagents used in Examples will be described.
[0128] NR: TSR 20
[0129] SBR1-1: Manufacturing Example 1-1
manufacture example 1-2
[0131] SBR2: Modified SBR (10 mass% styrene content, 40 mass% vinyl content, Mw: 60×10 4 )
[0132] BR: BR 150B manufactured by Ube Industries, Ltd. (cis content: 98% by mass)
[0133] Carbon black 1-1: IA 135mg / g
[0134] Carbon black 1-2: IA 160mg / g
[0135] Carbon black 2: SHOBLACK N220 (IA: 118 mg / g) manufactured by Cabot Japan Co., Ltd.
[0136] Silica: Ultrasil VN3 (N) produced by Degussa 2 SA: 175m 2 / g)
[0137] Wax: OZOACE0355 manufactured by Nippon Seika Co., Ltd.
[0138] Antiaging agent: NOCRAC 6C (N-phenyl-N'-(1,3-dimethylbutyl)-p-phenylenediamine) (6PPD) manufactured by Ouchi Shinko Chemical Industry Co., Ltd.
[0139] Stearic acid: Beaded stearic acid "Tsubaki" manufactured by NOF Corporation
[0140] Zinc oxide: Zinc oxide #2 manufactured by Mitsui Metal Mining Co., Ltd.
[0141] Silane coupling agent: Si69 (bis(3-triethoxysilylpropyl)tetrasulfide) manufactured by Degussa
[0142] Oil: TDAE oil produced by Japan Energy Co., Ltd.
[0143] Sulfur: powd...
manufacture example 1-1
[0147] Under a nitrogen atmosphere, add 3-dimethylaminopropyltrimethoxysilane to a 100ml volumetric flask, and then add anhydrous hexane to make a terminal modifier.
[0148] Add n-hexane, styrene, butadiene, and tetramethylethylenediamine to a pressure-resistant container fully substituted with nitrogen, and raise the temperature to 40°C. Next, after adding butyllithium, the temperature was raised to 50° C., followed by stirring. Next, a silicon tetrachloride / hexane solution was added and stirred. Next, the above-mentioned terminal modifier was added and stirred. After adding methanol in which 2,6-tert-butyl-p-cresol was dissolved to the reaction solution, the reaction solution was placed in a stainless steel container containing methanol, and aggregates were collected. The obtained aggregate was dried under reduced pressure for 24 hours to obtain SBR1-1. In the obtained SBR1-1, the styrene content was 27% by mass, the vinyl content was 57% by mass, and the Mw was 40×10 4...
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Abstract
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