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Acid for erosion of sandstone

A sandstone and erosion technology, applied in the field of chemical agents used in oil field development, can solve the problems of by-product precipitation, reduce the effect of oil well stimulation, affect the effect of oil well stimulation, etc., and achieve the effect of increasing permeability and realizing effective stimulation

Inactive Publication Date: 2003-07-30
王素君
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, in order to increase the production of oil wells with low permeability, the method of injecting acid into the oil well is generally used to make the acid react with the sandstone at the bottom of the oil well, corrode the sandstone, increase the permeability of the oil well, and achieve the purpose of increasing production. The acids used include hydrochloric acid, Hydrofluoric acid, phosphoric acid, sulfuric acid, etc., also include some potential acids such as esters, halogen salts, etc., and also include some compound acids, such as soil acid, capsule acid, etc., but there are two main disadvantages in using these acids: one is that these acids are different from Clay, silicate and other matrix non-consolidated substances in the near-wellbore react very quickly. Before the acid falls and the eroded sandstone at the bottom of the oil well, it fails or partially fails halfway, which greatly affects the stimulation effect of the oil well.
The second is that these acids react with the matrix non-consolidated matter near the wellbore to produce by-product precipitation, which also reduces the stimulation effect of the oil well

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Phosphonosuccinic acid 10 parts

[0025] Ammonium bifluoride 5 parts

[0026] Mannich base 1.5 parts

[0027] Concentration is 30% hydrochloric acid 5 parts

[0028] Dodecyl dimethyl benzyl ammonium chloride 1 part

[0029] 77.5 parts of water

[0030] Mixed to make the acid of this invention for etching sandstone.

Embodiment 2

[0032] Phosphonosuccinic acid 15 parts

[0033] Ammonium bifluoride 10 parts

[0034] 2 parts Mannich base

[0035] Concentration is 30% hydrochloric acid 8 parts

[0036] Dodecyltrimethylammonium Chloride 1 part

[0037] 64 parts of water

[0038] Mixed to make the acid of this invention for etching sandstone.

Embodiment 3

[0040] Phosphonosuccinic acid 20 parts

[0041] Ammonium bifluoride 10 parts

[0042] Mannich base 2.5 parts

[0043] Concentration is 30% hydrochloric acid 10 parts

[0044] Dodecyl dimethyl benzyl ammonium chloride 1 part

[0045] 51.5 parts of water

[0046] Mixed to make the acid of this invention for etching sandstone.

[0047] The acid used in the invention for eroding sandstone is not only applied to oil field stimulation, but also to natural gas and geothermal stimulation.

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PUM

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Abstract

The present invention discloses a sandstone acid, and its composition is formed from (wt%) phosphonobutanedioic acid 10-20%, ammonium bifluoride 5-15%, Mannich base 1.5-2.5%, hydrochloric acid 5-10%, dodecyl dimethyl benzyl ammonium chloride or dodecyl trimethyl ammonium chloride 1%, and the rest is water. The use of said sandstone acid can effectively raise well permeability to obtain the effect of raising oil production.

Description

Technical field: [0001] The invention relates to a chemical agent for oil field exploitation. Background technique: [0002] At present, in order to increase the production of oil wells with low permeability, the method of injecting acid into the oil well is generally used to make the acid react with the sandstone at the bottom of the oil well, corrode the sandstone, increase the permeability of the oil well, and achieve the purpose of increasing production. The acids used include hydrochloric acid, Hydrofluoric acid, phosphoric acid, sulfuric acid, etc., also include some potential acids such as esters, halogen salts, etc., and also include some compound acids, such as earth acid, capsule acid, etc., but there are two main disadvantages in using these acids: one is that these acids are different from Clay, silicate and other matrix non-consolidated substances in the near-wellbore react very quickly. Before the acid falls and corrodes the sandstone at the bottom of the oil w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23G1/02E21B43/27
Inventor 王素君
Owner 王素君