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Method for treating rare earth production tail water by utilizing abandoned mining pit

A technology for mines and rare earths, applied in mining wastewater treatment, aerobic process treatment, sustainable biological treatment, etc., can solve the problems of carbon-nitrogen ratio imbalance, lack of carbon source, water acidification and other problems

Inactive Publication Date: 2020-09-18
福州碧瑞源生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the in-situ rare earth mining process, due to the use of sodium sulfate leaching technology, the high ammonia nitrogen rare earth mining tail water after mine closure contains only nitrogen sources and lacks carbon sources due to the extremely high concentration of pollutants (2000-3000mg / L). The serious imbalance of carbon-nitrogen ratio and the acidification of water quality after ammonia nitrogen removal lead to unsatisfactory cost and effect of current treatment technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A method for treating rare earth production tail water by using an abandoned mine pit, comprising the following steps:

[0024] 1) Spread waterproof canvas on the inner surface of the pit, so that the pit forms an impermeable water collection space;

[0025] 2) Use a drainage pump to pump 10% of the total water in the pit from the water inlet of the pit into the high ammonia nitrogen rare earth mining tail water. Mining agent, leaching the rare earths in the soil, and then removing impurities through the impurity removal tank, collecting the rare earths in the sedimentation tank, and recycling the ammonium sulfate solution back to the in-situ leaching of the ore until all the rare earths in the mine are leached clean, and the residual after the mine is closed The high ammonia nitrogen rare earth mining tail water, the ammonia nitrogen concentration is 2000-3000mg / L;

[0026] 3) Microbial cells containing 10% of the total water in the pit are put into the above-mentione...

Embodiment 2

[0035] A method for treating rare earth production tail water by using an abandoned mine pit, comprising the following steps:

[0036] 1) Spread waterproof canvas on the inner surface of the pit, so that the pit forms an impermeable water collection space;

[0037] 2) Use a drainage pump to draw high ammonia nitrogen rare earth mining tail water with 15% of the total water volume of the mine pit from the water inlet of the mine pit. Mining agent, leaching the rare earths in the soil, and then removing impurities through the impurity removal tank, collecting the rare earths in the sedimentation tank, and recycling the ammonium sulfate solution back to the in-situ leaching of the ore until all the rare earths in the mine are leached clean, and the residual after the mine is closed The high ammonia nitrogen rare earth mining tail water, the ammonia nitrogen concentration is 2000-3000mg / L;

[0038] 3) Microbial cells with 15% of the total water in the pit were put into the above-...

Embodiment 3

[0047] A method for treating rare earth production tail water by using an abandoned mine pit, comprising the following steps:

[0048] 1) Spread waterproof canvas on the inner surface of the pit, so that the pit forms an impermeable water collection space;

[0049] 2) Use a drainage pump to draw high ammonia nitrogen rare earth mining tail water with 12% of the total water volume of the mine pit from the water inlet of the mine pit. Mining agent, leaching the rare earths in the soil, and then removing impurities through the impurity removal tank, collecting the rare earths in the sedimentation tank, and recycling the ammonium sulfate solution back to the in-situ leaching of the ore until all the rare earths in the mine are leached clean, and the residual after the mine is closed The high ammonia nitrogen rare earth mining tail water, the ammonia nitrogen concentration is 2000-3000mg / L;

[0050] 3) Microbial cells with 12% of the total water in the pit were put into the above-...

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Abstract

The invention discloses a method for treating rare earth production tail water by using an abandoned mining pit. The method comprises the following steps: 1) spreading waterproof canvas on the inner surface of the mining pit to form a water collecting space; 2) pumping high-ammonia-nitrogen rare earth mining tail water from a water inlet of the mining pit every day; 3) adding microbial thalli; 4)introducing oxygen into the mining pit, and controlling the dissolved oxygen content to be 1.5-2 mg / L; 5) when the concentration of ammonia nitrogen in the mining pit exceeds 15 mg / L, continuously supplementing microbial thalli into the mining pit; 6) when the ammonia nitrogen index of the rare earth mining tail water in the abandoned mining pit does not exceed 15 mg / L, achieving up-to-standard discharge, and achieving overflow water outlet through daily water inlet; and 7) in the tail water treatment process, enabling a large number of beneficial microorganisms to grow to form flocs which canbe used for raising fries. The abandoned mining pit with low field environment cost is utilized, meanwhile, high-concentration ammonia nitrogen tail water generated by rare earth mining can be efficiently treated, and the problem of pollution to the environment is relieved.

Description

technical field [0001] The invention belongs to the technical field of sludge treatment, and in particular relates to a method for treating rare earth production tail water by utilizing an abandoned mine pit. Background technique [0002] In the in-situ rare earth mining process, due to the use of sodium sulfate leaching technology, the high ammonia nitrogen rare earth mining tail water after mine closure contains only nitrogen sources and lacks carbon sources due to the extremely high concentration of pollutants (2000-3000mg / L). The serious imbalance of carbon-nitrogen ratio and the acidification of water quality after ammonia nitrogen removal lead to unsatisfactory cost and effect of current treatment technology. Contents of the invention [0003] The object of the present invention is to provide a method for treating rare earth production tail water by using abandoned mine pits in view of the above phenomenon. [0004] In order to achieve the above object, the present ...

Claims

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Application Information

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IPC IPC(8): C02F3/34C02F3/32C02F3/02C02F101/16C02F103/10
CPCC02F3/34C02F3/347C02F3/325C02F3/02C02F2101/16C02F2103/10Y02W10/10
Inventor 郑尚煌姚灵丹
Owner 福州碧瑞源生物科技有限公司
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