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Organic electroluminescent device for adjusting light-emitting wavelength based on negative thermal expansion effect of anti-perovskite material and preparation method thereof

An anti-perovskite, negative thermal expansion technology, applied in the direction of electric solid device, semiconductor/solid state device manufacturing, electrical components, etc. The effect of improving color purity

Pending Publication Date: 2020-11-17
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is: in order to solve the technical problem that the existing single light-emitting device can only emit light of a fixed wavelength, which is not conducive to the integration and intelligence of the light-emitting device, the present invention provides a method for adjusting the light-emitting wavelength based on the negative thermal expansion effect of the anti-perovskite material Organic electroluminescence device and preparation method thereof

Method used

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  • Organic electroluminescent device for adjusting light-emitting wavelength based on negative thermal expansion effect of anti-perovskite material and preparation method thereof

Examples

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Embodiment 1

[0027] Such as figure 1 As shown, the organic electroluminescent device provided in this embodiment based on the negative thermal expansion effect of the anti-perovskite structure material to adjust the luminous wavelength includes a glass substrate 1 coated with a semi-reflective conductive electrode layer 2, the The semi-reflective conductive electrode layer 2 is sequentially vapor-deposited with a hole injection layer 3 , a hole transport layer 4 doped with an inverse perovskite structure material, an electron transport layer and a light emitting layer 5 , and a metal electrode layer 6 from bottom to top.

[0028] The semi-reflective conductive electrode layer 2 adopts an Ag electrode with a thickness of 15 nm.

[0029] The hole injection layer adopts 3 MnO with a thickness of 10nm 3 .

[0030] The hole transport layer 4 of the doped anti-perovskite structure material adopts the doped anti-perovskite structure material Mn with a thickness of 50nm. 3 Zn 0.5 sn 0.5 N's N...

Embodiment 2

[0042] On the basis of Example 1, the difference between this Example and Example 1 is that the anti-perovskite structure material is replaced by Mn 3 (Zn 0.6 sn 0.4 )(N 0.85 C 0.15 ).

[0043]Under standard test conditions, when the electroluminescent device is placed at ordinary room temperature (about 25°C, at this time, the anti-perovskite material has no thermal expansion effect), the peak wavelength of the emission spectrum is 528nm. When the device is placed in an environment of 42°C and the thickness of the hole transport layer is reduced to 45nm, the peak wavelength of the emission spectrum is 482nm, and the blue shift is 48nm. When the device is placed in an environment of 15°C to expand the thickness of the hole transport layer to 55nm, the peak wavelength of the emission spectrum is 625nm, and the red shift is 97nm. The temperature controls the peak wavelength of the emission spectrum, thereby controlling the emission color.

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Abstract

The invention discloses an organic electroluminescent device capable of adjusting the light-emitting wavelength based on the negative thermal expansion effect of an anti-perovskite material and a preparation method of the organic electroluminescent device, and relates to the technical field of organic electroluminescence. The organic electroluminescent device comprises a glass substrate, a semi-reflective conductive electrode layer is plated on the glass substrate, and a hole injection layer, a hole transport layer doped with the anti-perovskite structure material, an electron transport layer,a light emitting layer and a metal electrode layer are sequentially evaporated on the semi-reflective conductive electrode layer from bottom to top. The organic electroluminescent device has the function of controlling the wavelength of the organic electroluminescent device by controlling the external temperature, and the preparation method is simple, efficient and is suitable for the large-scaleproduction.

Description

technical field [0001] The invention relates to the technical field of organic electroluminescence, and more specifically relates to an organic electroluminescence device and a preparation method thereof based on the negative thermal expansion effect of an anti-perovskite material for adjusting the emission wavelength. Background technique [0002] Compared with traditional light-emitting devices, organic electroluminescent devices have the advantages of thinness, short response time, strong drop resistance, simple production, low cost, and low energy consumption. They are widely used in many consumer electronics products, health care, environmental protection, etc. aspect. By using the optical microcavity structure, the emission peak can be narrowed, the color purity can be improved, the intensity of the emission peak can be enhanced and the wavelength of the emission peak can be adjusted, the luminous intensity of the device can be improved and the luminous color can be ch...

Claims

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Application Information

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IPC IPC(8): H01L51/50H01L51/52H01L51/56
CPCH10K50/17H10K50/852H10K71/00
Inventor 钟建刘泽宇贾晓伟刘洁尘李娜
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA