Degradable and high-toughness composite material and preparation method thereof

A composite material, strong and tough technology, applied in medical science, surgery, etc., can solve the problems of fast degradation rate, insufficient mechanical properties of composite materials, poor connection performance, etc.

Active Publication Date: 2021-02-09
珠海中科先进技术研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] Degradable magnesium alloys have good biocompatibility and are well applied in the field of medical implant devices, but there are the following problems: 1. Magnesium alloys are used in The degradation rate in the human body is too fast. When the magnesium alloy plays a supporting or connecting role in the body, the degradation rate of the magnesium alloy is too fast, which is not conducive to the recovery of some diseases; 2. In order to overcome the first problem, it is usually necessary to combine magnesium alloys with Other alloy materials are made into composite materials together to reduce its degradation rate, but this makes the mechanical properties of co

Method used

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  • Degradable and high-toughness composite material and preparation method thereof
  • Degradable and high-toughness composite material and preparation method thereof
  • Degradable and high-toughness composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0116] Embodiment 1: the preparation of composite material

[0117] A flat plate-shaped degradable, strong and tough composite material, by volume percentage, including 39% of the zinc alloy layer, 1% of the intermediate alloy layer and 60% of the magnesium alloy layer; the intermediate alloy layer is composed of magnesium-zinc alloy powder; the zinc alloy layer The layer does not contain Mg; the magnesium alloy layer does not contain Zn.

[0118] The zinc alloy layer is composed of zinc alloy, and zinc alloy, by mass percentage, includes the following components:

[0119] Y 3.5%

[0120] Nd 3.0%;

[0121] The magnesium alloy layer is made of magnesium alloy, and the magnesium alloy, by mass percentage, includes the following components:

[0122] Y 3.5%

[0123] Nd 3.0%;

[0124] The preparation method of above-mentioned zinc alloy comprises the following steps:

[0125] (1) Weigh Y, Nd, Zn (residue) according to the proportion, then vacuum smelting, the temperature of v...

Embodiment 2

[0140] Embodiment 2: the preparation of composite material

[0141] A flat plate-shaped degradable, strong and tough composite material, by volume percentage, including 29% of the zinc alloy layer, 2% of the intermediate alloy layer and 69% of the magnesium alloy layer; the intermediate alloy layer is composed of magnesium-zinc alloy powder; the zinc alloy layer The layer does not contain Mg; the magnesium alloy layer does not contain Zn.

[0142] The zinc alloy layer is composed of zinc alloy, and zinc alloy, by mass percentage, includes the following components:

[0143]

[0144]

[0145] The magnesium alloy layer is made of magnesium alloy, and the magnesium alloy, by mass percentage, includes the following components:

[0146]

[0147] The preparation method of above-mentioned zinc alloy comprises the following steps:

[0148] (1) Weigh Y, Nd, Mn, Ca, Sn, Zn (remainder) according to the proportion, and then vacuum smelt. The temperature of vacuum smelting is 680...

Embodiment 3

[0162] Embodiment 3: the preparation of composite material

[0163] A kind of degradable, strong and tough composite material in the shape of a round bar. According to the volume percentage, from the outside to the inside, there are 39% of the zinc alloy layer, 1% of the intermediate alloy layer and 60% of the magnesium alloy layer; the intermediate alloy layer is composed of magnesium Composed of zinc alloy powder; the zinc alloy layer does not contain Mg; the magnesium alloy layer does not contain Zn.

[0164] The zinc alloy layer is composed of zinc alloy, and zinc alloy, by mass percentage, includes the following components:

[0165] Y 3.0%

[0166] Nd 2.5%

[0167] Mn 1.0%;

[0168] The magnesium alloy layer is made of magnesium alloy, and the magnesium alloy, by mass percentage, includes the following components:

[0169] Y 3.0%

[0170] Nd 2.5%

[0171] Mn 1.0%;

[0172] The preparation method of zinc alloy, magnesium alloy and magnesium-zinc alloy powder is the ...

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Abstract

The invention belongs to the technical field of alloy materials, and discloses a degradable and high-toughness composite material and a preparation method thereof. The composite material comprises a zinc alloy layer, an intermediate alloy layer and a magnesium alloy layer, wherein the intermediate alloy layer is composed of a magnesium-zinc alloy, the zinc alloy layer does not contain Mg, the magnesium alloy layer does not contain Zn, the zinc alloy layer is composed of a zinc alloy, the zinc alloy further comprises Y and/or Nd, the magnesium alloy layer is composed of a magnesium alloy, the magnesium alloy further comprises Y and/or Nd, and the magnesium-zinc alloy comprises the following components in percentage by mass: 50-80% of Mg and 20-50% of Zn. Due to the existence of the intermediate alloy layer in the composite material, the connection between the zinc alloy layer and the magnesium alloy layer is enhanced, the mechanical property of the composite material is improved, and particularly, an elastic modulus of the composite material is obviously reduced relative to an elastic modulus of the zinc alloy, so that the healing of bone tissues is not influenced, and a degradationrate of the composite material in a human body is reduced.

Description

technical field [0001] The invention belongs to the technical field of alloy materials, in particular to a degradable, strong and tough composite material and a preparation method thereof. Background technique [0002] Degradable magnesium alloys have good biocompatibility and are well applied in the field of medical implant devices, but there are the following problems: 1. The degradation rate of magnesium alloys in the human body is too fast. When magnesium alloys support or When connecting, because the degradation rate of magnesium alloy is too fast, it is not conducive to the recovery of some diseases; 2. In order to overcome the first problem, it is usually necessary to make magnesium alloy and other alloy materials into a composite material to reduce its degradation rate, however This in turn makes the mechanical properties of the composite insufficient. For example, the elastic modulus of the composite material is too high (>50GPa), resulting in a "stress shieldin...

Claims

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Application Information

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IPC IPC(8): A61L31/12A61L31/02A61L31/14A61L31/16B22F7/04C22C18/00C22C23/06C22C23/04
CPCA61L31/022A61L31/14A61L31/16B22F7/04C22C18/00C22C23/06C22C23/04A61L2300/102A61L2300/412B22F2007/042
Inventor 马国睿吴锋
Owner 珠海中科先进技术研究院有限公司
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