Rapidly-formed halogen-free flame-retardant PA6 composite material and preparation method thereof

A composite material and fast technology, applied in the field of composite materials, can solve the problems of injection mold release difficulty, long molding cycle, and lower production efficiency, and achieve the goal of maintaining physical properties and flame retardancy, shortening injection molding cycle, and improving production efficiency Effect

Inactive Publication Date: 2021-05-04
扬州集飞新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Halogen-free flame retardants are mainly phosphorus compounds and metal hydroxide compounds. These two types of compounds do not volatilize and do not produce corrosive gases when burned. They are called non-disclosure flame retardants. Among the existing technologies, there are many developments and applications of halogen-free flame-retardant PA6, but at present, there are generally situations where the molding cycle is long or injection mold release is difficult, and there are relatively few researches and developments on rapid prototyping, and there are few public records. involves
In the injection molding process of the existing halogen-free flame-retardant PA6 materials, there are often situations such as mold sticking and mold release top deformation. The lengthening of the molding cycle reduces the production efficiency

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] In the embodiment of the present invention, a rapid prototyping halogen-free flame-retardant PA6 composite material, the raw materials according to the mass percentage include:

[0022] PA6 resin: 76.9%;

[0023] MPP: 15%;

[0024] MCA: 3%;

[0025] Zinc borate: 3%;

[0026] Superfine talcum powder: 0.5%;

[0027] Lubricant PETS: 1%;

[0028] Antioxidant 1098: 0.3%;

[0029] Antioxidant 168: 0.3%.

[0030] The preparation method of the rapid prototyping halogen-free flame-retardant PA6 composite material, the specific steps are as follows:

[0031] (1) Weigh each raw material according to weight percentage;

[0032] (2) Add PA6 resin, superfine talc powder, antioxidant 1098, antioxidant 168 and lubricant PETS to the first high mixer and mix for 3 minutes to obtain a PA6 resin mixture;

[0033] (3) Add MPP, MCA and zinc borate to the second high mixer and mix for 3 minutes to obtain a flame retardant mixture;

[0034] (4) Adjust the temperature of the extruder s...

Embodiment 2

[0039] In the embodiment of the present invention, a rapid prototyping halogen-free flame-retardant PA6 composite material, the raw materials according to the mass percentage include:

[0040] PA6 resin: 73.9%;

[0041] MPP: 15%;

[0042] MCA: 6%;

[0043] Zinc borate: 3%;

[0044] Superfine talcum powder: 0.5%;

[0045] Lubricant PETS: 1%;

[0046] Antioxidant 1098: 0.3%;

[0047] Antioxidant 168: 0.3%.

[0048] The preparation method of the rapid prototyping halogen-free flame-retardant PA6 composite material, the specific steps are as follows:

[0049] (1) Weigh each raw material according to weight percentage;

[0050] (2) Add PA6 resin, superfine talc powder, antioxidant 1098, antioxidant 168 and lubricant PETS to the first high mixer and mix for 3 minutes to obtain a PA6 resin mixture;

[0051] (3) Add MPP, MCA and zinc borate to the second high mixer and mix for 3 minutes to obtain a flame retardant mixture;

[0052] (4) Adjust the temperature of the extruder s...

Embodiment 3

[0057] In the embodiment of the present invention, a rapid prototyping halogen-free flame-retardant PA6 composite material, the raw materials according to the mass percentage include:

[0058] PA6 resin: 68.4%;

[0059] MPP: 16%;

[0060] MCA: 9%;

[0061] Zinc borate: 3%;

[0062] Superfine talcum powder: 1%;

[0063] Lubricant PETS: 1%;

[0064] Antioxidant 1098: 0.3%;

[0065] Antioxidant 168: 0.3%.

[0066] The preparation method of the rapid prototyping halogen-free flame-retardant PA6 composite material, the specific steps are as follows:

[0067] (1) Weigh each raw material according to weight percentage;

[0068] (2) Add PA6 resin, superfine talc powder, antioxidant 1098, antioxidant 168 and lubricant PETS to the first high mixer and mix for 3 minutes to obtain a PA6 resin mixture;

[0069] (3) Add MPP, MCA and zinc borate to the second high mixer and mix for 3 minutes to obtain a flame retardant mixture;

[0070](4) Adjust the temperature of the extruder so t...

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Abstract

The invention relates to a rapidly-formed halogen-free flame-retardant PA6 composite material and a preparation method thereof. The rapidly-formed halogen-free flame-retardant PA6 composite material comprises the following raw materials in percentage by mass: 65-80% of PA6 resin; 15-25% of a phosphorus-nitrogen composite flame retardant; 3-5% of a synergistic flame retardant; 0.5-2% of a nucleating agent; 0.5 to 1% of an antioxidant; and 1-2% of a lubricant. The prepared rapid prototyping halogen-free flame-retardant PA6 composite material does not contain halogen, meets the green and environment-friendly requirements, has the characteristics of rapid prototyping, shortening of the injection molding period and the like, is especially suitable for injection molding of thin-wall plastic products, effectively shortens the molding period during injection molding of the material, and improves the production efficiency. Meanwhile, the physical property and the flame retardant property of the material are kept.

Description

technical field [0001] The invention belongs to the technical field of composite materials, and in particular relates to a rapid prototyping halogen-free flame-retardant PA6 composite material and a preparation method thereof. Background technique [0002] Halogen-free flame retardants are mainly phosphorus compounds and metal hydroxide compounds. These two types of compounds do not volatilize and do not produce corrosive gases when burned. They are called non-disclosure flame retardants. Among the existing technologies, there are many developments and applications of halogen-free flame-retardant PA6, but at present, there are generally situations where the molding cycle is long or injection mold release is difficult, and there are relatively few researches and developments on rapid prototyping, and there are few public records. involves. In the injection molding process of the existing halogen-free flame-retardant PA6 materials, there are often situations such as mold stic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08K5/3492C08K3/38C08K3/34C08K5/20C08K5/526C08K13/02
CPCC08K5/34928C08K3/38C08K3/34C08K5/20C08K5/526C08K13/02C08L2201/02C08L2201/22C08K2201/014C08K2003/387C08L77/02
Inventor 史有井凡坚魏习军
Owner 扬州集飞新材料科技有限公司
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