Carrier-free high-gloss oil black color master batch as well as preparation method and application thereof
A high-gloss, carrier-free technology, applied in the field of color masterbatch, can solve the problems of low content of color masterbatch, no carrier resin, adverse effects on products, etc.
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[0042] The second aspect of the present invention provides a method for preparing the carrier-free high-gloss oil black masterbatch, which includes the following steps: weighing each material according to the formula, putting them into a high-speed stirring pot for mixing in turn, mixing the stirred The material is put into a twin-screw extruder, extruded and granulated to obtain a carrier-free high-gloss oil black masterbatch.
[0043] As a preferred technical solution, the mixing time is 3-8 minutes; the extrusion temperature in the extrusion granulation process is 150-200°C.
[0044] As a further preferred technical solution, the mixing time is 5 minutes; the extrusion temperature in the first zone and the second zone temperature are 160±5°C, and the extrusion temperature in the third zone is 160±5°C. and the temperature of the fourth zone is 165±5°C, the extrusion temperature of the fifth zone and the sixth zone of the extrusion temperature is 170±5°C, and the extrusion te...
Embodiment 1
[0054] In order to solve the above technical problems, the first aspect of the present invention provides a carrier-free high-gloss oil black masterbatch. The raw materials include the following components, in parts by weight, 40 parts of carbon black, 40 parts of dye, 18 parts of dispersant, Antioxidant 2 parts.
[0055] The carbon black is carbon black M880 (CAS No.: 1333-86-4). The carbon black M880 was purchased from Shanghai Kaiyin Chemical Co., Ltd.
[0056] The dyes include oil-soluble dyes and solvent dyes.
[0057] The oil-soluble dye is oil-soluble black B (CAS No.: 149315-87-7), and the solvent dye includes Solvent Red 179 (CAS No.: 6829-22-7) and Solvent Green 5 (CAS No.: 2744-50 -5).
[0058] The oil-soluble black B was purchased from Suzhou Sanwei Dye Chemical Co., Ltd. The solvent red 179 was purchased from Wenzhou Meiernuo Chemical Co., Ltd. The solvent green 5 was purchased from Shanghai Jizhi Biochemical Technology Co., Ltd.
[0059] The dispersant is a...
Embodiment 2
[0072] A carrier-free high-gloss oil black masterbatch, the specific implementation method is the same as that of Example 1, except that 35 parts of carbon black, 30 parts of dye, 15 parts of dispersant, and 1 part of antioxidant. Wherein said each component by weight, carbon black M880 is 35 parts, oil soluble black B is 26 parts, solvent red 179 is 7 parts, solvent green 5 is 7 parts, dispersant EVA3 is 15 parts, antioxidant 1010 is 0.7 parts, and antioxidant 168 is 0.3 parts.
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