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Biaxially stretched polyester film roll

A biaxially stretched, polyester film technology, used in other household appliances, flat products, household appliances, etc., can solve the problem of undocumented properties of the film foreign matter film, and achieve excellent transparency, less foreign matter, and less antimony content. Effect

Active Publication Date: 2021-09-28
TOYOBO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is no description about the method of reducing foreign matter in the membrane and the desired membrane properties.

Method used

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  • Biaxially stretched polyester film roll
  • Biaxially stretched polyester film roll
  • Biaxially stretched polyester film roll

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0209] The above-mentioned polyester 1 and polyester 2 were mixed at a weight ratio of 96:4 and fed into an extruder. Then, the mixed resin was melted at 270°C, cooled to 260°C, extruded from a T-die, wound on a rotating metal roll whose surface temperature was cooled to 30°C, and quenched to obtain an undrawn sheet with a thickness of 220 µm. Stretching film. The take-up speed (rotation speed of the metal roll) of the unstretched film at this time was about 80 m / min. The Tg of the unstretched film was 75°C, and the Tm was 256°C. In addition, in order to prevent foreign matter from adhering, a laser cleaner is installed on the cooled metal roll.

[0210] The obtained unstretched sheet was heated to 110°C, stretched in the longitudinal direction at a total stretch ratio of 4.5 times by two-stage stretching in which the first step was set to 1.5 times and the second step was set to 3 times . Next, in the transverse stretching process (hereinafter referred to as tenter), stre...

Embodiment 2

[0215] A biaxially stretched polyester film roll was obtained in the same manner as in Example 1 except that polyester 1 and polyester 2 were mixed at a weight ratio of 94:6 and charged into an extruder. Table 2 shows the film forming process conditions and cutting conditions, and Table 3 and Table 4 show the evaluation results. It is a film of good quality.

Embodiment 3

[0217] The biaxially stretched polyester film roll was obtained by the method similar to Example 1 except having changed the thickness of a film into 6 micrometers, and having made the roll length of a roll into 30000 m. Table 2 shows the film forming process conditions and cutting conditions, and Table 3 and Table 4 show the evaluation results. It is a film of good quality.

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Abstract

To provide a polyester film roll that: has a very low antimony content; contains little foreign material; has an excellent transparency and heat resistance; is not only resistant to the occurrence of slack in film roll immediately after film production, but also is resistant to the occurrence of slack in film roll with elapsed time even over long-term storage; and exhibits an excellent printability and processability. A film roll provided by winding a biaxially stretched polyester film that has an antimony content in the film of not more than 10 ppm, a phosphorus content of 25-75 ppm, and an arithmetic mean roughness for the film surface of 0.02-0.05 mum, the biaxially stretched polyester film roll being characterized by satisfying the following requirements (1) to (6): (2) the winding length of the film roll is 8,000-80,000 m; (2) the width of the film roll is 500-4,000 mm; (3) in a measurement of the hardness of the surfacemost layer of the film roll at intervals of 50 mm in the film width direction, the average hardness is in the range of 500-700; (4) in the measurement of the hardness of the surfacemost layer of the film roll at intervals of 50 mm in the film width direction, the variation in the hardness is 10%-20%; (5) the film thickness is 5-40 mum; and (6) with regard to the thickness variation in the film width direction at the surface layer of the film roll, the thickness pattern has locations that form depressions and, in the depression having the largest thickness difference (the largest depression), the thickness variation for the largest depression, as calculated from the average film thickness and the largest thickness difference at the largest depression, is not more than 10%.

Description

technical field [0001] The present invention relates to a biaxially stretched polyester film roll excellent in hygienic properties. Specifically, it relates to a roll that does not cause wrinkles after long-term storage after being formed into a film, and does not cause problems in processing steps such as printing and bag making. Biaxially stretched polyester film rolls used for food packaging bags, labels, etc. Background technique [0002] Polyester resins such as polyethylene terephthalate (PET) and polybutylene terephthalate (PBT), which are thermoplastic resins with excellent heat resistance and mechanical properties, are used in plastic films, electronics, energy, It is used in many fields such as packaging materials and automobiles. Among plastic films, biaxially stretched PET films are widely used in industrial and packaging fields because of their excellent balance between mechanical property strength, heat resistance, dimensional stability, chemical resistance, o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C55/12B29K67/00B29L7/00C08L67/00C08J5/18C08K3/08
CPCB29C55/12C08J5/18C08G63/183C08L67/02C08G63/84C08G63/87B29C48/08B29C48/0018B29C48/305B29C48/92B29C2948/92704B29C55/143C08J2367/02C08J2467/02B29C48/88B29C48/28C08K3/08C08L67/00B29C48/307B29K2067/003
Inventor 春田雅幸多保田规
Owner TOYOBO CO LTD
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