Carbazolyl conjugated polymer, and preparation method of electric storage device thereof
A conjugated polymer, polymer technology, applied in the direction of electrical solid device, semiconductor/solid state device manufacturing, electrical components, etc., can solve the problem of polyfluorene device turn-on voltage increase, limit carrier migration rate, raw material and manufacturing cost Advanced problems, to achieve the effect of improving thermodynamic and electrochemical stability, enhancing hole or electron transport ability, and reducing process cost
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[0056] The present invention provides a kind of preparation method of described carbazole-based conjugated polymer, the method comprises the following steps:
[0057] Step 1, adding carbazole monomer and nitrogen-containing monomer into the solvent, heating and reacting to obtain a polymer solution;
[0058] Step 2, post-processing the polymer solution to obtain a carbazole-based conjugated polymer.
[0059] Step 1. Adding carbazole monomer and nitrogen-containing monomer into a solvent, heating and reacting to obtain a polymer solution.
[0060]The carbazole monomer is N-alkylcarbazole. The alkyl group is an alkyl group containing 3 to 31 carbon atoms, preferably an alkyl group containing 6 to 21 carbon atoms, more preferably 7-tridecyl, 8-pentadecyl and 9-heptadecyl alkyl.
[0061] Preferably, the 2 and 7 positions of the carbazole monomer have a boronic acid group or a boronic acid ester group, such as an alkyl boronic acid group, an aryl boronic acid group, an alkenyl b...
Embodiment 1
[0131] in N 2 Under the atmosphere, put 1.49g of 2,3-naphthalene dicarboxylic anhydride, 0.27g of 3,6-dibromo-1,2-phenylenediamine, and 10mL of glacial acetic acid into the reaction vessel, stir and raise the temperature to 108°C, reflux the solvent, and carry out Constant temperature reaction for 6 hours.
[0132] After the reaction, the reaction solution was cooled to room temperature, and the crude product was gradually precipitated, filtered, and washed with deionized water until neutral. The obtained crude product was put into a vacuum drying oven for drying, the temperature of vacuum drying was 85°C, the time of vacuum drying was 12 hours, and the pressure of vacuum drying was -30KPa. The crude product after drying was separated and purified by column chromatography. The stationary phase of the chromatography column was silica gel powder, and the liquid phase was a mixture of dichloromethane:petroleum ether with a volume ratio of 3:1 to obtain the nitrogen-containing mo...
Embodiment 2
[0137] The substrate layer with the ITO cathode layer was placed in deionized water, absolute ethanol, acetone, absolute ethanol, and deionized water in sequence for cleaning for 30 minutes each. After cleaning, it was stored in absolute ethanol.
[0138]The carbazole-based conjugated polymer prepared in Example 1 was dissolved in toluene to obtain a polymer solution with a concentration of 5 mg / mL. The above polymer solution was added dropwise on the cleaned cathode layer, uniformly dispersed by a homogenizer, and the toluene solvent was removed by vacuum drying to obtain an organic layer with a thickness of 90 nm.
[0139] The metal electrode Al is attached on the organic layer by vacuum evaporation method, the thickness and area of the metal electrode are 300nm and 1.0mm respectively 2 . A sandwich structure electromechanical storage device of the Flash memory type is obtained, and the structure schematic diagram is as follows figure 1 shown.
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