Adhesive sheet, method for producing adhesive sheet, method for producing intermediate laminate, and intermediate laminate
A manufacturing method and adhesive layer technology, applied in chemical instruments and methods, synthetic resin layered products, film/sheet adhesives, etc., and can solve the problems of external light reflection, reflective glare, etc.
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Embodiment 1
[0494] 95 parts by mass of butyl acrylate, 5 parts by mass of acrylic acid, 0.2 parts by mass of azobisisobutyronitrile as a polymerization initiator, and 233 parts by mass of ethyl acetate as a solvent was passed through nitrogen gas, and nitrogen substitution was performed for about 1 hour while stirring. Then, it heated to 60 degreeC, and it was made to react for 7 hours, and the solution of the adhesive polymer whose weight average molecular weight (Mw) was 600000 was obtained.
[0495] To the solution of the adhesive polymer, 0.075 parts by mass of TETRAD C as a crosslinking agent was added to 100 parts by mass of the adhesive polymer in the solution of the adhesive polymer. 100 parts by mass of the adhesive polymer in the solution is 2 parts by mass of BLACK ND1 (leuco dye), which is a compound colored by acid, relative to the adhesive polymer in the solution of the adhesive polymer 100 parts by mass of 10 parts by mass of CP-310B (photoacid generator) as an acid genera...
Embodiment 2
[0502] A pressure-sensitive adhesive sheet was produced in the same manner as in Example 1 except that UVA-TAC was used as the substrate B and the second pressure-sensitive adhesive layer A was used as the second pressure-sensitive adhesive layer.
[0503] In addition, the 2nd adhesive layer A was produced by the following method.
[0504] (Preparation of the second adhesive layer A)
[0505] 63 parts by mass of 2-ethylhexyl acrylate (2EHA), 15 parts by mass of N-vinylpyrrolidone (NVP), methyl 9 parts by mass of methyl acrylate (MMA), 13 parts by mass of hydroxyethyl acrylate (HEA), 0.2 parts by weight of azobisisobutyronitrile as a polymerization initiator, 233 parts by weight of ethyl acetate as a solvent, and nitrogen gas , nitrogen substitution was performed for about 1 hour while stirring. Then, it heated at 60 degreeC, it was made to react for 7 hours, and the 3rd adhesive composition whose weight average molecular weight (Mw) was 1,200,000 was obtained.
[0506] A po...
Embodiment 3
[0508] A pressure-sensitive adhesive sheet was produced in the same manner as in Example 1 except that UVA-TAC was used as the substrate B and UVA-OCA was used as the second pressure-sensitive adhesive layer.
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