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Lithium metal battery module and charging and discharging control method

A lithium metal battery, charge and discharge control technology, applied in the field of battery charge and discharge, can solve the problem of inability to accurately control the discharge voltage and current of lithium metal battery cells, reduce the cycle performance of lithium metal battery modules, and adversely affect lithium metal single cells. It can reduce the performance difference, eliminate lithium dendrites, and reduce the cost of batteries.

Pending Publication Date: 2021-11-23
ZHEJIANG FUNLITHIUM NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. According to the existing charging method, the charging current of the lithium metal battery module is relatively large, resulting in the deposition of lithium on the surface of the negative electrode of the single cell of the lithium metal battery at a relatively fast rate, which is prone to uneven deposition and lithium branches. Crystal, greatly reducing the cycle performance of lithium metal battery modules;
[0005] 2. According to the existing discharge method, it can only be discharged according to the same discharge circuit as the charging process, and it is impossible to accurately control the discharge voltage and current of each single lithium metal battery cell. However, the researchers of this application have conducted long-term research Accidentally found that the same charge-discharge current ratio is very unfavorable to the cycle performance of lithium metal single cells;
[0006] 3. Due to the long-term use of lithium battery cells after leaving the factory, certain performance differences will gradually occur between each lithium battery cell, so there are inconsistencies between multiple lithium battery cells in the same lithium metal battery module , Lithium metal battery modules will cause greater differences in the state of lithium battery cells (such as SOC, voltage, etc.) after continuous charge and discharge cycles, that is, the difference between multiple lithium battery cells in the same lithium metal battery module The inconsistency between them becomes larger after continuous charge and discharge cycles, resulting in overcharge or overdischarge of some lithium metal single cells during charging, which will accelerate the performance degradation of lithium metal battery modules and eventually lead to premature failure of lithium battery modules

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A lithium metal battery module, including a plurality of lithium metal battery monomer cells and battery management systems, battery management systems include transformation efficiency adjustable transformer system, all lithium metal battery cells are separate from the battery management system, respectively Connection, the battery management system controls all of the lithium metal battery cells according to the current voltage input and output, and the radical parallel group is used to adjust the voltage to the rated voltage through the transformer system to adjust the voltage to the rated voltage.

[0029] Among them, the negative electrode of the lithium metal battery monomer cell is a metal negative electrode of lithium metal, lithium indium alloy, lithium copper alloy, lithium tin alloy, lithium magnesium alloy, and other lithium-containing sheet material. The power conversion efficiency of the conversion efficiency adjustable transformer system is 60% to 100%.

Embodiment 2

[0031] A lithium metal battery module and a charge and discharge control method, including a plurality of lithium metal battery cells and battery management systems, battery management systems include transformers that are adjustable, charging, battery management system control all lithium The metal battery monomer cell or all of the first cells are combined with the joint group. Among them, each of the first electrical cells is combined by no more than 3 lithium metal cells, and during charging, the lithium metal battery cells in the first cell combination are in series.

[0032] The battery management system detects the end voltage of the lithium metal battery in real time. When the end voltage of the lithium metal battery is greater than the rated voltage of the charging, the battery management system adjusts the end voltage of the lithium metal battery module to the rated voltage by the transformer system. .

Embodiment 3

[0034] A charge and discharge control method of a lithium metal battery module, including a plurality of lithium metal battery cells and battery management systems, battery management systems include transformers that can be adjusted by conversion efficiency, when discharged, battery management system controls all lithium The metal battery monomer cell or the second battery cell combination is discharged one by one, wherein each second battery cell combination consists of no more than 3 lithium metal battery cells, and during discharge, the second battery is combined. Lithium metal battery monomer cells are parallel.

[0035] The battery management system detects the end voltage of the lithium metal battery in real time. When the end voltage of the lithium metal battery is less than the rated voltage of the discharge, the battery management system adjusts the end voltage of the lithium metal battery module to the rated voltage by the transformer system. .

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PUM

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Abstract

The invention belongs to the technical field of battery manufacturing, and discloses a lithium metal battery module and a charge and discharge control method. The battery module comprises a plurality of lithium metal battery single cells and a battery management system, the battery management system comprises a transformation system with adjustable conversion efficiency, all the single lithium metal battery cells are separately connected with the battery management system, and during charging, the battery management system controls all the single lithium metal battery cells or all the first battery cell combinations to be connected in parallel; during discharging, the battery management system controls the lithium metal battery monomer cells or the second cell combination to discharge one by one; and the battery management system detects the terminal voltage of the lithium metal battery connection group in real time, and adjusts the terminal voltage of the lithium metal battery connection group to the rated voltage through the voltage transformation system, so that the cycle performance of the lithium metal battery module can be effectively improved, and the service life of the lithium metal battery module is prolonged.

Description

Technical field [0001] The present invention relates to the field of battery charge and discharge technologies, and more particularly to a lithium metal battery module and a charge and discharge control method. Background technique [0002] The lithium metal battery module consists of a plurality of lithium metal battery cells. Conventional lithium metal battery modules The charge and discharge mode employed is: skewer in a fixed manner according to the rated voltage required by the electric device, and then charge and discharge. [0003] If the lithium metal battery module obtained by the conventional module assembly method has the following issues: [0004] 1, according to the existing charging method, the charging current of the lithium metal battery module is large, resulting in a lithium metal battery cell negative electrode surface to deposit in a faster rate, and it is easy to uniformly deposit to produce a lithium branch. The crystal greatly reduces the cycle performance ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H02J7/00H01M10/44
CPCH02J7/0024H02J7/0025H02J7/00302H02J7/00306H02J7/0063H02J7/0068H01M10/441Y02E60/10
Inventor 许晓雄崔言明秦晨阳龚和澜戈志敏
Owner ZHEJIANG FUNLITHIUM NEW ENERGY TECH CO LTD
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