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Production process of super-clean biodiesel with metal ion content less than 2PPM

A technology of metal ions and biodiesel, applied in the fields of biofuel, petroleum industry, fatty acid production, etc., can solve the problem of difficult and efficient removal of metal ions and non-metal ions in biodiesel, and achieve the effect of efficient removal

Active Publication Date: 2021-12-10
湖北天基生物能源科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to overcome the above-mentioned technical deficiencies, provide a production process of ultra-clean biodiesel with a metal ion content of less than 2PPM, and solve the technical problem that it is difficult to efficiently remove metal ions and non-metal ions in biodiesel in the prior art

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] The present embodiment proposes a production process of ultra-clean biodiesel with a metal ion content less than 2PPM, comprising the following steps:

[0047] S1, adding clay and activated carbon to the crude first fat and stirring, then centrifuged to obtain the first oil; the addition of the clay is 3.5% of the quality of the crude oil; the addition of the activated carbon is 3% of the quality of the crude oil 0.3%; wherein, the crude methyl ester is obtained by esterification of crude oil and methanol;

[0048] S2. Adding water to the first grease to wash to obtain a second grease; the amount of water added is 15% of the mass of the first grease;

[0049] S3. Distilling the second grease for the first time at 205°C and a vacuum residual pressure of 5000Pa to obtain a third grease;

[0050] S4. Distilling the third grease for a second time at 225° C. and a vacuum residual pressure of 900 Pa to obtain biodiesel.

Embodiment 2

[0052] The present embodiment proposes a production process of ultra-clean biodiesel with a metal ion content less than 2PPM, comprising the following steps:

[0053] S1, adding clay and activated carbon to the crude methyl fat and stirring, then centrifuged to obtain the first oil; the addition of the clay is 4% of the quality of the crude oil; the amount of the activated carbon is 4% of the quality of the crude oil 0.25%; wherein, the crude methyl ester is obtained by esterification of crude oil and methanol;

[0054] S2. Adding water to the first grease for washing to obtain a second grease; the amount of water added is 14% of the mass of the first grease;

[0055] S3. Distilling the second grease for the first time at 200°C and a vacuum residual pressure of 4900Pa to obtain a third grease;

[0056] S4. Distilling the third grease for a second time at 220° C. and a vacuum residual pressure of 900 Pa to obtain biodiesel.

Embodiment 3

[0058] The present embodiment proposes a production process of ultra-clean biodiesel with a metal ion content less than 2PPM, comprising the following steps:

[0059] S1, adding clay and activated carbon to the crude methyl fat and stirring, then centrifuged to obtain the first oil; the addition of the clay is 3% of the quality of the crude oil; the amount of the activated carbon is 3% of the quality of the crude oil 0.2%; wherein, the crude methyl ester is obtained by esterification of crude oil and methanol;

[0060] S2. Adding water to the first grease for washing to obtain a second grease; the amount of water added is 10% of the mass of the first grease;

[0061] S3. Distilling the second grease for the first time at 200°C and a vacuum residual pressure of 4500Pa to obtain a third grease;

[0062]S4. Distilling the third grease for a second time at 220° C. and a vacuum residual pressure of 800 Pa to obtain biodiesel.

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Abstract

The invention discloses a production process of super-clean biodiesel with the metal ion content smaller than 2 PPM, and belongs to the technical field of biodiesel preparation. The production process comprises the following steps: S1, adding carclazyte and activated carbon into crude methyl ester, stirring, and then centrifugally separating to obtain first grease; S2, adding water into the first grease for washing to obtain second grease; S3, carrying out first distillation on the second grease at the temperature of 200-210 DEG C under the vacuum residual pressure of 4500-5000Pa to obtain third grease; and S4, carrying out secondary distillation on the third grease at 220-230 DEG C under the vacuum residual pressure of 800-900 Pa to obtain the biodiesel. The detection result of sodium, potassium and phosphorus in the biodiesel obtained by the production process can be less than 1PPM, the sulfur content can be less than 5PPM, and efficient removal of metal ions and non-metal ions in the biodiesel is realized.

Description

technical field [0001] The invention relates to the technical field of biodiesel preparation, in particular to a production process of ultra-clean biodiesel with a metal ion content of less than 2PPM. Background technique [0002] The crude methyl ester produced by the esterification reaction of crude oil and methanol usually contains metal ions and non-metal ions. These metal ions and non-metal ions are usually organic trace elements such as RCOOK, RCOONa, organic phosphorus, and organic sulfur, and K , Na, P, S and other water-soluble trace elements, it is difficult to efficiently remove metal ions and non-metal ions in biodiesel by methods of the prior art. Contents of the invention [0003] The purpose of the present invention is to overcome the above technical deficiencies, provide a production process of ultra-clean biodiesel with a metal ion content of less than 2PPM, and solve the technical problem that it is difficult to efficiently remove metal ions and non-metal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/02C11C1/08C11C1/10
CPCC10L1/02C11C1/08C11C1/10Y02E50/10
Inventor 冀星钟民强邓金华李丽李建峰刘曌卿迟姚玲常青冀旌语刘卓卿
Owner 湖北天基生物能源科技发展有限公司