Self-cleaning plastic rain shoe with super-amphiphobic coating layer
A super-amphiphobic, self-cleaning technology, applied in coatings, footwear, polyurea/polyurethane coatings, etc., can solve the problems of oily sludge, difficult to clean, easy to be invaded by the external environment, etc., to achieve good hydrophobicity Sexuality and oleophobicity, durability enhancement, amphiphobic stabilization effects
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Embodiment 1
[0028] A self-cleaning plastic rain boot with a superamphiphobic coating, the surface of the plastic rain boots is sprayed with a superamphiphobic coating, and its preparation method comprises the following steps:
[0029] S1. Add 80 parts of PVC resin, 5 parts of carbon black, 1 part of diethylene glycol, 30 parts of plasticizer, 0.5 part of toughening agent and 0.2 part of anti-aging agent into a twin-screw extruder at a temperature of 110 ° C to mix and granulate, Add the obtained composite plastic granules into the injection molding machine under the pressure of 10Mpa to cast and form, and obtain the rain boots blank after demoulding, and then use the cutting tool to trim the burrs of the rain boots blank;
[0030] S2, using 3-isocyanate group methylene-3,5,5-trimethylcyclohexyl isocyanate and polyoxypropylene diol as raw materials to prepare hydrophobic water-based polyurethane emulsion, through the interaction between octadecyl isocyanate and titanium dioxide surface hydr...
Embodiment 2
[0042] A self-cleaning plastic rain boot with a superamphiphobic coating, the surface of the plastic rain boots is sprayed with a superamphiphobic coating, and its preparation method comprises the following steps:
[0043]S1. Add 100 parts of PVC resin, 10 parts of carbon black, 3 parts of diethylene glycol, 40 parts of plasticizer, 1 part of toughening agent and 0.5 part of anti-aging agent into a twin-screw extruder and mix and granulate at 110°C. Add the obtained composite plastic granules into the injection molding machine under the pressure of 14Mpa to cast and form, and obtain the rain boots blank after demoulding, and then use the cutting tool to trim the rough edge of the rain boots blank;
[0044] S2, using 3-isocyanate group methylene-3,5,5-trimethylcyclohexyl isocyanate and polyoxypropylene diol as raw materials to prepare hydrophobic water-based polyurethane emulsion, through the interaction between octadecyl isocyanate and titanium dioxide surface hydroxyl Prepare...
Embodiment 3
[0056] A self-cleaning plastic rain boot with a superamphiphobic coating, the surface of the plastic rain boots is sprayed with a superamphiphobic coating, and its preparation method comprises the following steps:
[0057] S1. Add 90 parts of PVC resin, 8 parts of carbon black, 2 parts of diethylene glycol, 35 parts of plasticizer, 0.8 part of toughening agent and 0.4 part of anti-aging agent into a twin-screw extruder and mix and granulate at 120°C. Add the obtained composite plastic granules into the injection molding machine and pour them under the pressure of 12Mpa, and obtain the rain boots blank after demoulding, and then use the cutting tool to trim the burrs of the rain boots blank;
[0058] S2, using 3-isocyanate group methylene-3,5,5-trimethylcyclohexyl isocyanate and polyoxypropylene diol as raw materials to prepare hydrophobic water-based polyurethane emulsion, through the interaction between octadecyl isocyanate and titanium dioxide surface hydroxyl Prepare modifi...
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