Preparation method of color vision correction resin lens
A resin lens, color vision technology, applied in the field of ophthalmic optics, can solve the problems of unacceptable appearance of bright red and green, decreased vision, indistinguishability, etc., and achieves good rigidity, improved vividness, and sensitive spectral response.
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Embodiment 1
[0064] Embodiment 1: Preparation of organic / inorganic nanocomposite microspheres and color vision correction lenses
[0065] (1) Preparation of organic / inorganic nanocomposite microspheres:
[0066] (1) Take 3g of emulsifier RF-345 and add it to 1200g of pure water. After it is completely dissolved, add 35g of nano-iron oxide, add 150g of sodium acetate saturated aqueous solution dropwise within 70min, and then add 20g of crosslinking agent DAP; Enter nitrogen, add 150 g of dichloromethane solvent containing spiropyran compound (formula I) (spiropyran 35 g solvent 115 g), add methyl acrylate monomer 18 g and ethyl acrylate monomer 10 g, stir and heat up to 65 ° C, add Initiator ammonium persulfate 0.1g, keep warm for 18h, filter, wash and dry to obtain acrylate / spiropyran / iron oxide deep red nanospheres. The yield was 85%.
[0067] (2) The product prepared in step (1) is observed with a JEM-2100 transmission electron microscope, as figure 1 As shown, it can be seen that the...
Embodiment 2
[0072] Embodiment 2: Preparation of organic / inorganic nanocomposite microspheres and color vision correction lenses
[0073] (1) Preparation of organic / inorganic nanocomposite microspheres:
[0074] 1. Take 2.5g of emulsifier RF-345 and add it to 1100g of pure water. After it is completely dissolved, add 30g of nano-copper oxide, add 120g of sodium acetate saturated aqueous solution dropwise within 70min, and then add 20g of cross-linking agent DAP; Enter nitrogen, add 145g of dichloromethane solvent containing spiropyran compound (formula I) (spiropyran 35g solvent 110g), add methyl acrylate monomer 18g and ethyl acrylate monomer 10g, stir and heat up to 65 ° C, add Initiator ammonium persulfate 0.1g, keep warm for 16h, filter, wash and dry to obtain acrylate / spiropyran / copper oxide nanospheres. The yield was 82%.
[0075] 2. The product prepared in step 1 is observed with a transmission electron microscope, as figure 2 As shown in the figure, it can be seen that the appe...
Embodiment 3
[0081] Example 3: Preparation of organic / inorganic nanocomposite microspheres and color vision correction lenses
[0082] (1) Preparation of organic / inorganic nanocomposite microspheres:
[0083] a. Take 2.4g of emulsifier sodium dodecylbenzenesulfonate and add it to 1000g of pure water. After it is completely dissolved, add 30g of nano-cobalt oxide, add 140g of sodium acetate saturated aqueous solution dropwise within 70min, and then add the crosslinking agent butyl acrylate 20g; feed nitrogen into the reaction kettle, add 145g of dichloromethane solvent containing spiropyran compound (formula I) (105g of spiropyran 40g solvent), add 28g of methyl acrylate monomer, stir and heat up to 65°C, add Initiator sodium persulfate 0.1g, keep warm for 16h, filter, wash and dry to obtain acrylate / spiropyran / cobalt oxide nanospheres. The yield was 80%.
[0084] b. the product prepared in step a is observed through a transmission electron microscope, such as image 3 As shown in the fi...
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