The invention relates to a polycyclic
boron-containing compound and an electronic device thereof. By introducing the
boron element, the compound with rigid structural characteristics is constructed, and the
rigid structure can effectively inhibit vibration relaxation caused by
molecular vibration and rotation, thereby being beneficial to enhancing the
fluorescence quantum yield of the molecules and reducing the half-peak width of the luminescent spectrum. In addition, due to the
rigid structure, the molecules have excellent film-forming property and
thermal stability, and the stability of thedevice can be further improved; in addition, since the polycyclic
boron-containing compound is positioned at the 1 or 4 positions of
carbazole and fluorenyl elements, no isomer is generated during preparation, and purification is facilitated. The electroluminescent device prepared from the compound provided by the invention has the advantages of low driving
voltage, high luminous efficiency, longservice life, high
spectral color purity and the like. In addition, the preparation method of the polycyclic boron-containing compound is simple, raw materials are easy to obtain, the materials are easy to purify, and the industrial development requirement can be met.