Zero-emission-oriented high-salt high-fluorine mine water purification system and process
A technology for purification process and mine water, applied in mining wastewater treatment, water pollutants, chemical instruments and methods, etc., can solve the problem that mine water process is difficult to achieve high-efficiency water purification and zero discharge at the same time
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Embodiment 1
[0064] This embodiment provides a zero-emission-oriented high-salt and high-fluorine mine water purification system, such as figure 1 Shown, comprise water inlet pipeline 1, the water outlet end of water inlet pipeline 1 is connected with the first water inlet end of bipolar membrane device 2, and the lye outlet end of bipolar membrane device 2 is connected with the inlet of filtrate-mixture preparation device 3 The alkali liquid end is connected, the acid liquid end of the bipolar membrane device 2 is connected with the acid liquid end of the filtrate-mixture preparation device 3; the alkali liquid end of the filtrate-mixture preparation device 3 is connected with the liquid inlet end of the high-density pool 4 Connected, the outlet mixture end of filtrate-mixture preparation device 3 is communicated with the inlet mixture end of membrane coagulation reactor 5;
[0065] The water inlet end of the high density pool 4 is connected with the water inlet adjustment pool 6, the wat...
Embodiment 2
[0072] This embodiment provides a zero-discharge-oriented high-salt and high-fluorine mine water purification process, which adopts the zero-discharge-oriented high-salt and high-fluorine mine water purification system in Example 1; the process includes the following steps:
[0073] Step 1, preparing an acidic mixture and an alkaline filtrate;
[0074] Step 1.1, prepare mixed acid solution and lye;
[0075] Pure water is passed into the bipolar membrane device 2 through the water inlet pipe 1, and NaCl, Na 2 SO 4 and NaOH are added to the bipolar membrane device 2, NaCl and Na 2 SO 4 Dissolve in pure water as the raw material solution, and dissolve NaOH in pure water as the electrode chamber solution. The operating pressure used in the preparation is 40V, the operating current is 3A, and the operating time is 58min; NaCl and NaCl 2 SO 4 The concentration of NaOH is 0.2mol / L, the concentration of NaOH is 0.07mol / L, NaCl, Na 2 SO 4 The molar ratio to NaOH is 20:20:7.
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