Method for adulterating adjuvant, hot-pressing sintered block titanium silicon carbide ceramic material
A technology for hot-pressing sintering and titanium silicon carbide is applied in the field of hot-pressing sintering layered titanium silicon carbide bulk materials mixed with an additive CaF2, which can solve the problems of difficulty in synthesizing titanium silicon carbide, difficulty in development and utilization, etc., and achieves low cost, Accelerates solid-phase reactions, improves purity and density
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Embodiment 1
[0022] The molar ratio is Ti:Si:C=3:1:1.95 and 5wt% CaF is added 2 100 g of the mixed powder was densely put into a graphite mold and sintered under an Ar protective atmosphere. The heating rate is 50°C / min, the sintering temperature is 1300°C, the pressure is 30MPa, and the temperature is kept for 2 hours. The density of the bulk material is 99%, Ti 3 SiC 2 The content is 97.1wt.%. Compressive strength ≥ 800MPa, three-point bending strength σ h ≥420MPa,K IC ≥5MPa·m 1 / 2 .
Embodiment 2
[0024] The molar ratio is Ti:Si:C=3:1:2.05 and 3wt% CaF 2 200 grams of mixed powders were put into a graphite mold densely and sintered under an Ar protective atmosphere. The heating rate is 50°C / min, the sintering temperature is 1400°C, the pressure is 60MPa, and the temperature is kept for 6 hours. The density of the bulk material is 99.7%, Ti 3 SiC 2 The content is 98.5wt.%. Compressive strength ≥ 800MPa, three-point bending strength σ h ≥500MPa, K IC ≥5MPa·m 1 / 2 .
[0025] The compressive strength, three-point flexural strength and fracture toughness of the above materials were tested on INSTRON-1195 universal material testing machine. During the three-point bending strength test, the loading rate of the test strip is 0.5mm / min, and the span is 25mm. The fracture toughness is measured by the unilateral notched beam method, the notch is in the middle of the length direction of the test bar, the depth is 2.5mm, the support span is 20mm, and the loading rate is 0.5mm / ...
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