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Pure oxygen replaced coal gasifying method and its coal gasifying apparatus

A technology for coal gasification and pure oxygen, applied in the field of coal gasification, can solve the problems of large energy consumption, low gas calorific value, high energy consumption and the like

Inactive Publication Date: 2006-10-11
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The conventional coal gasification method mainly realizes the gasification of coal through partial combustion. When air is used as the gasification medium, the calorific value of the coal gas is low and accompanied by the formation of nitrogen oxides; using pure oxygen as the gasification medium can avoid The generation of nitrogen oxides increases the calorific value of the gas, but the production of pure oxygen requires a large amount of energy (such as for coal gasification power generation, which can account for more than 10% of the power consumption rate of the plant), so pure oxygen is used as the gas The method and device for producing gas from chemical media have the disadvantage of high energy consumption

Method used

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  • Pure oxygen replaced coal gasifying method and its coal gasifying apparatus

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Embodiment 1

[0020] A pure oxygen replacement coal gasification method using an oxygen carrier to carry out low ash coal / coal coke / petroleum coke similar to pure oxygen oxidized coal gasification, characterized in that the metal sulfide as an oxygen carrier is placed in a circulating fluidized bed Inside, the fluidizing air is introduced from the lower part of the circulating fluidized bed, and the metal sulfide reacts with the oxygen in the air to obtain metal sulfate, and then the metal sulfate separated by the separator enters from the small opening of the trumpet-shaped return leg. , is discharged from the large mouth end of the trumpet-shaped return leg and enters the bubbling fluidized bed. Fuel is added to the bubbling fluidized bed, and the refluidization gas enters the bubbling fluidized bed from the lower part of the bubbling fluidized bed. The carbon in the fluidized bed fuel undergoes a reduction reaction with metal sulfate to produce carbon monoxide and metal sulfide. After bei...

Embodiment 2

[0022] A coal gasification device for the pure oxygen replacement coal gasification method described in Example 1, consisting of a circulating fluidized bed 1 and a bubbling fluidized bed 3, metal sulfides are placed in the circulating fluidized bed 1, and in the circulating fluidized bed 1 The lower end of the fluidized bed 1 is provided with a fluidized air inlet A, and the lower end of the bubbling fluidized bed 3 is provided with a fluidized gas inlet C, which is characterized in that an oxygen-depleted air separator is connected to the upper part of the circulating fluidized bed 1 5. The lower end of the oxygen-poor air separator 5 is connected with a trumpet-shaped return leg 6 and the lower end of the oxygen-deficient air separator 5 is connected with the small port of the trumpet-shaped return leg 6, and the large port of the trumpet-shaped return leg 6 is connected with the The lower part of the bubbling fluidized bed 3 is connected, and the upper part of the bubbling ...

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Abstract

The pure oxygen substituted coal gasifying process comprises setting metal sulfide into circular fluidizing bed and leading fluidizing air in from the bottom for reaction between metal sulfide and oxygen to obtain metal sulfate; making the metal sulfate enter to the bubbling fluidized bed via belled material returning leg, feeding fuel to the bubbling fluidized bed and making the fluidizing gas enter the bubbling fluidized bed from the bottom for reduction reaction between carbon and metal sulfate to produce CO. The coal gasifying apparatus consists of circular fluidizing bed and bubbling fluidized bed, the circular fluidizing bed has metal sulfide set inside it and fluidizing air inlet in the bottom, and the bubbling fluidized bed has fluidizing gas inlet in the lower end, poor-oxygen air separator connected to the upper part and gas separator connected to the upper part.

Description

technical field [0001] The invention relates to a method and device for using an oxygen carrier to gasify low-ash coal / coal / petroleum coke similar to pure oxygen gasification, in particular to a pure oxygen replacement coal gasification method and a coal gasification device. Background technique [0002] One of the sustainable development strategies of energy utilization is to realize the efficient and clean utilization of energy. Coal is the largest fossil energy, and coal gasification is the main method to realize efficient and clean utilization of coal. The conventional coal gasification method mainly realizes the gasification of coal through partial combustion. When air is used as the gasification medium, the calorific value of the coal gas is low and accompanied by the formation of nitrogen oxides; using pure oxygen as the gasification medium can avoid The generation of nitrogen oxides increases the calorific value of the gas, but the produc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10J3/54
Inventor 向文国李政
Owner SOUTHEAST UNIV
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