Silver halides color photographic sensitive material and color image forming method
A technology of color photography and photosensitive materials, applied in photosensitive materials, applications of photosensitive materials, optics, etc., can solve problems such as the dependence of exposure temperature and the stability of processing factors that have not been discussed
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Embodiment 1
[0342] Emulsion (preparation of B-11~14) control example: silver chloride cube, side length 0.46 microns
[0343] High silver chloride cubic particles were prepared by a conventional method of simultaneously adding and mixing silver nitrate and sodium chloride to a stirred aqueous gelatin solution. Among them, potassium bromide is added during the period of adding 80% to 90% of silver nitrate. Inside, add K 4 [Ru(CN) 6 ]. And during the period of adding 83% to 88% of silver nitrate, adding K 2 [IrCl 6 ], during the period of adding silver nitrate 90% to 95%, adding K 2 [Ir(5-methylthiazole)Cl 5 ]. After desalting the obtained emulsion, gelatin was added to redisperse it. The resulting particles are cubic emulsions with side lengths of 0.46 microns and a coefficient of variation of 9.5% surrounded by six parallel {110} faces.
[0344] Dissolve the emulsion at 40°C, add sensitizing pigment Dye-1 and sodium thiosulfonate, add sodium thiosulfate pentahydrate as a sulfur s...
Embodiment 2
[0617] For sample B (111), the photo constituent layers were changed as follows to prepare a thinner sample.
[0618] The first layer (blue sensitive emulsion layer)
[0619] Emulsion B-11 0.14
[0620] Gelatin 0.75
[0621] Yellow coupler (ExY-2) 0.34
[0622] Color image stabilizer (Cpd-1) 0.04
[0623] Color image stabilizer (Cpd-2) 0.02
[0624] Color image stabilizer (Cpd-3) 0.04
[0625] Color image stabilizer (Cpd-8) 0.01
[0626] Solvent (Solv-1) 0.13
[0627] The second layer (anti-mixing color layer)
[0628] Gelatin 0.60
[0629] Anti-mixing agent (Cpd-19) 0.09
[0630] Color image stabilizer (Cpd-5) 0.007
[0631] Color image stabilizer (Cpd-7) 0.007
[0632] Ultraviolet absorber (UV-C) 0.05
[0633] Solvent (Solv-5) 0.11
[0634] The third layer (green emulsion layer)
[0635] Emulsion G-1 0.12
[0636] Gelatin 0.73
[0637] Magenta coupler (ExM) 0.15
[0638] Ultraviolet absorber (UV-A) 0.05
[0639] Color image stabilizer (Cpd-2) 0.02
[0640] C...
Embodiment 3
[0686] Using samples B(111)-B(154) and B(211)-B(254), images were formed by laser scanning exposure.
[0687] As a laser light source, the following light source is used: using LiNbO with an inversion region structure 3 The SHG crystal, for YAG solid-state laser (resonance wavelength 946nm) with semiconductor laser GaAlAs (resonance wavelength 808.5nm) as the excitation light source, the 473nm light emitted after wavelength conversion; using LiNbO with inversion region structure 3 The SHG crystal of YVO with semiconductor laser GaAlAs (resonant wavelength 808.7nm) as the excitation light source 4 Solid-state laser (resonant wavelength 1064 nm), 532 nm light emitted after wavelength conversion; and AlGaInP (resonant wavelength about 680 nm, model No. LN9R20 manufactured by Matsushita Electric). Each of the three colors of laser light moves vertically through the multi-faceted mirror relative to the scanning direction, and scans and exposes the sample sequentially. By maintain...
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