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Method for changing inclination angle of hydride gas phase transverse epitaxy GaN film

A hydride vapor phase and lateral epitaxy technology, which is applied to electrical components, gaseous chemical plating, coating, etc., can solve the problem of high dislocation density of GaN epitaxial layer

Inactive Publication Date: 2004-11-10
NANJING UNIV
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Problems solved by technology

The outstanding disadvantage of this method is that the dislocation density in the GaN epitaxial layer is very high, generally up to 10 10 cm -2 about

Method used

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  • Method for changing inclination angle of hydride gas phase transverse epitaxy GaN film
  • Method for changing inclination angle of hydride gas phase transverse epitaxy GaN film
  • Method for changing inclination angle of hydride gas phase transverse epitaxy GaN film

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Embodiment Construction

[0014] The main method of the hydride vapor phase epitaxy device and the lateral epitaxial growth technology used in the present invention is to directly introduce a certain amount of HCl into the substrate surface, and by changing the chemical reaction balance in the reaction zone, the tilt angle of the GaN lateral epitaxial film finally changes. Change or even eliminate to obtain a high-quality flat GaN film.

[0015] The growth conditions are: the lateral epitaxial substrate is GaN / sapphire; the window area / SiO 2 The ratio of the mask area is 2:20, SiO 2 The mask orientation is along the GaN direction. NH 3 The flow rate was 600 sccm, and the HCl flow rate to generate GaCl was 1 sccm. The HCl flow rate added directly to the substrate was 4-10 sccm. figure 2 The example of the photograph is a flow rate of 5 sccm of HCl added directly to the substrate. The lateral epitaxial growth temperature is 1050°C.

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Abstract

The invention is a technique and method to change and eliminate crystal surface included angle by adding HCl during the course of transversely extending film GaN by HVPE method. It directly adds HCl to the surface of a substrate, by the corrosion by HCl to GaN, etc, makes local V / III ratio change, so as to change the included angle and improve surface feature and quality of the film, where the flux of HCl is 4-10sccm. Compared with other methods, it does not introduce extra impurities, and this is a main technical characteristic. In addition, to introduce HCl into growth region can change local reaction balance and also improve the surface feature and quality of the film GaN.

Description

1. Technical field [0001] The invention relates to a technology and a method for changing and eliminating the tilt angle generated in the growth process by directly adding HCl in the process of lateral epitaxial growth of a GaN thin film by using the hydride vapor phase epitaxy (HVPE) technology. 2. Technical background [0002] Group III-V nitride materials (also known as GaN-based materials), mainly composed of GaN, InGaN, and AlGaN alloy materials, are new semiconductor materials that have attracted much attention in the world in recent years. Their superior performance makes them a short-wavelength semiconductor optoelectronic The most preferred material for devices and high-frequency, high-voltage, high-temperature microelectronic devices. [0003] Due to the limitations of the physical properties of GaN itself, the growth of GaN bulk single crystal is very difficult and has not been put into practical use. In the early days, people mainly used the hydride vapor phase ...

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Application Information

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IPC IPC(8): C23C16/34H01L21/20H01L21/205
Inventor 张荣修向前汪峰于英仪谢自力俞慧强李斌斌顾书林沈波江若琏施毅朱顺明韩平胡立群郑有炓
Owner NANJING UNIV
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