In-mold appearance coatings for nylon and nylon based thermoplastic substrates
An inner coating, thermoplastic technology, used in the field of thermosetting mold inner and outer surface coating, urethane-acrylate
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[0007] The composition of the in-mold and exterior coatings of the present invention is based on a thermosetting copolymeric composition comprising urethane acrylate oligomers, sulfonic acid functional acrylate monomers and acrylic monomers, the remainder being copolymerizable diacrylates and and / or copolymerizable monoethylenically unsaturated monomers, wherein mixtures of diacrylates and monomers are preferred.
[0008] The first thing to talk about is urethane-acrylate oligomers. Acrylate-functional reactive oligomers are low-molecular-weight urethane intermediates terminated with acrylate or methacrylate. A preferred urethane intermediate comprises the reaction product of an excess of isocyanate, preferably diisocyanate, with a small amount of polyol, preferably diol, resulting in an isocyanate-terminated low molecular weight linear urethane intermediate. The urethane intermediate is further reacted with a hydroxyalkyl acrylate to produce an acrylate functional oligomer te...
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