Non-aqueous electrolyte battery
A non-aqueous electrolyte and battery technology, used in non-aqueous electrolyte batteries, electrolyte battery manufacturing, lithium batteries, etc., can solve problems such as difficulty in fully improving safety, and achieve the effect of improving overcharge characteristics and suppressing internal short circuits
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[0076] [preliminary test]
[0077] The above-mentioned electron beam cross-linked separators (used in batteries A1, A3, B1, and C1 of the present invention described later and comparative batteries X4, Y3, and Z3) and heat-resistant layer-laminated separators (used in batteries of the present invention described later) were studied. A2, A4 and comparative battery X5), the cut-off temperature (hereinafter sometimes referred to as SD temperature) and membrane rupture temperature (hereinafter sometimes referred to as is the MD temperature), and the results are shown in Table 1. In addition, the production method of the evaluation battery, the evaluation device, and the measurement method of SD temperature and MD temperature are as follows.
[0078] [How to make an evaluation battery (cell)]
[0079] Such as Figure 5 As shown, two cell sheets 14 were prepared in which a substantially square aluminum foil (thickness: 15 μm) 12 was arranged on one surface of a glass substrate 11...
Embodiment 1
[0092] As Example 1, the battery shown in the best mode for carrying out the above invention was used.
[0093] The thus fabricated battery is hereinafter referred to as the inventive battery A1.
Embodiment 2
[0095] A battery was produced in the same manner as in Example 1 above except that a heat-resistant layer-laminated separator was used instead of an electron beam-crosslinked separator as the separator.
[0096] The battery thus fabricated is hereinafter referred to as the inventive battery A2.
[0097] Here, the heat-resistant layer-laminated separator was produced by the method shown below.
[0098] First, polyamide (PA), which is a water-insoluble heat-resistant material, is dissolved in a solution of N-methyl-2-pyrrolidone (NMP) as a water-soluble solvent, and polycondensation is performed at a low temperature in the solution to produce polyamide-doped liquid. Next, the dopant solution is applied to one side of a polyethylene (PE) microporous membrane as a base material to a predetermined thickness, then immersed in water to remove the water-soluble NMP solvent, and at the same time carry out water-insoluble Precipitation / coagulation of polyamides. Thus, a microporous p...
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