Hardmask for improved reliability of silicon based dielectrics
a silicon-based dielectric and hard-mask technology, applied in the field of integrated circuits, can solve the problems of poor quality and reliability, low k dielectric reliability, and prior-art reliability problems, and achieve the effects of improving reliability, reliable electrical characteristics, and reducing the risk of failure or deformation of the chip interconnect structur
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[0075] In this example, four different OMCATS-containing hardmasks (HMs) of the present invention were made by PECVD using the conditions in the following table.
TABLEOMCATSOMCATSOMCATSOMCATSHM 1HM 2HM 3HM 4300 mm300 mm300 mm200 mm*OMCATS Flow2000250028001800(mgm)O2 Flow (sccm)01602200He Carrier100010001000500Flow (sccm)Temp. (° C.)350350350350Pressure (Torr)5555Spacing (mils)450450450450HF power (W)500500400500LF power (W)01506075
*For OMCATS HM 4 prepare in 200 mm Plasma CVD system (Column 5), typical electrical breakdown plots, breakdown plot and J-E plot are shown in FIGS. 2A and 2B. It can be seen from the plots that this film had excellent breakdown properties of 8 MV / cm and a low electrical leakage of less than 2 × 10E−9 A / cm2 at 2 MV / cm.
[0076] The FTIR spectrum shown in FIG. 3 reveals a typical plasma SiCOH film structure with stable Si—O, S1—CH3, Si—H and cross-linking S1—CH2—Si bonding in the film. The typical Auger Profile (FIG. 4) of SiCOH film without O2 precursor show...
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