Oxidizing device with increased oxidizing performance and method of manufacturing the same
a technology of oxidizing device and oxidizing performance, which is applied in the direction of electrolysis organic production, electrolysis components, separation processes, etc., can solve the problems of difficulty in producing active oxygen species, inadequate oxidizing capability of catalyst for carbon containing substances like carbon or ch/sub>4 /sub>that are chemically stable, etc., to achieve increased oxidizing capability, high oxidizing performance, and increased oxidizing performance
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First Embodiment
[0062]An oxidizing device of a first embodiment according to the present invention will be described below with reference to FIG. 1 of the accompanying drawings.
[0063]As shown in FIG. 1, the oxidizing device 1 of the present embodiment includes a proton conductive body 2 and an electrode member 3 placed on the proton conductive body 2 for oxidizing a carbon-containing component 5 in a gaseous mixture containing H2O 4 and a carbon-containing component 5.
[0064]The proton conductive body 2 has a conducting rate of 0.01 Scm−1or more at a temperature of 400° C. or less.
[0065]The electrode member 3 includes an anode electrode portion 31 and a cathode electrode portion 32 held in contact with each other. The electrode member 3 allows a proton (H+) to be separated from H2O 4 placed in contact with a boundary portion between the anode electrode portion 31 and the proton conductive body 2 to facilitate a reaction introducing the proton into the proton conductive body 2. Furthe...
second embodiment
[0082]With the present embodiment, three kinds of oxidizing devices are prepared in structures including the proton conductive bodies of the first embodiment containing compositions of TiP2O7, Ba Ce0.85Y0.15O3-α and La0.9Sr0.1Sc3-α, respectively.
[0083]The proton conductive bodies had electric conductivities of MP2O7 (M=Sn, Ti) (under a condition of 250° C., the electric conductivities can be described as 5.8×10−2 Scm−1>>BaCe0.85Y0.15O3-α (under a condition of 400° C., the electric conductivities can be described as 1.0×10−2 Scm−1)>>La0.9Sr0.1ScO3-α) (under a condition of 500° C., the electric conductivities can be described as 1.4×10−3 Scm−1) in this order.
[0084]Further, tests were conducted to evaluate generation start temperatures of generating active oxygen and the amounts of generated active oxygen in the same methods conducted in the tests of the first embodiment. Results are indicated in FIG. 3. For comparison purposes, tests were also conducted on oxidizing devices incorporat...
third embodiment
[0090]With the present embodiment, oxidizing devices are prepared using proton conductive bodies (Sn0.9In0.1P2O7 (under a condition of 250° C., the electric conductivity is 0.194 Scm−1) and Ti0.95Al0.5P2O7 (under a condition of 250° C., the electric conductivity is 0.181 Scm−1)) having improved electric conductivities by adding In and Al as dopants to metallic sites of SnP2O7 and TiP2O7 of the proton conductive bodies.
[0091]Further, tests were conducted to evaluate generation start temperatures of generating active oxygen and the amounts of generated active oxygen in the same methods conducted in be tests of the first embodiment. Results are indicated in FIG. 4. For comparison purposes, tests were also conducted on oxidizing devices employing SnP2O7 and only CB, respectively, with results being indicated in FIG. 4.
[0092]In FIG. 4, the abscissa axis indicates a temperature (° C.) and the ordinate axis indicates the amount (μmol / min) of generated CO2.
[0093]It turns out from FIG. 4 tha...
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Abstract
Description
Claims
Application Information
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