Check patentability & draft patents in minutes with Patsnap Eureka AI!

Oxidizing device with increased oxidizing performance and method of manufacturing the same

a technology of oxidizing device and oxidizing performance, which is applied in the direction of electrolysis organic production, electrolysis components, separation processes, etc., can solve the problems of difficulty in producing active oxygen species, inadequate oxidizing capability of catalyst for carbon containing substances like carbon or ch/sub>4 /sub>that are chemically stable, etc., to achieve increased oxidizing capability, high oxidizing performance, and increased oxidizing performance

Inactive Publication Date: 2009-10-01
NIPPON SOKEN +1
View PDF1 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides an oxidizing device that can use H2O in a gaseous mixture containing H2O and a carbon-containing component as a reactant, resulting in increased oxidizing performance. The device includes a proton conductive body with an electric conductivity of 0.01 Scm−1 or more at a temperature of 400° C or less. The device also includes an anode electrode and a cathode electrode in contact with the proton conductive body, allowing for the separation of protons from H2O and the introduction of the protons into the proton conductive body. The cathode electrode facilitates a reduction reaction with the carbon-containing component, while the anode electrode facilitates the separation of protons from H2O. The device can generate active oxygen species that react with the carbon-containing component to oxidize it. The high electric conductivity of the proton conductive body allows for the autonomous taking in of protons separated from H2O, while the captured protons can freely move about in the electrodes. The device can be used to oxidize the carbon-containing component in the gaseous mixture.

Problems solved by technology

However, with such a technology proposed in the related art described above, an active oxygen species can be produced merely from a cathode electrode with a resultant disadvantage in which the catalyst has inadequate oxidizing capability for carbon containing substances like carbon or CH4 that are chemically stable.
Further, the active oxygen species reacts rapidly with reduction gases such as H2 and HC under the same atmosphere, causing an issue to arise with a difficulty of producing the active oxygen species.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Oxidizing device with increased oxidizing performance and method of manufacturing the same
  • Oxidizing device with increased oxidizing performance and method of manufacturing the same
  • Oxidizing device with increased oxidizing performance and method of manufacturing the same

Examples

Experimental program
Comparison scheme
Effect test

embodiments

First Embodiment

[0062]An oxidizing device of a first embodiment according to the present invention will be described below with reference to FIG. 1 of the accompanying drawings.

[0063]As shown in FIG. 1, the oxidizing device 1 of the present embodiment includes a proton conductive body 2 and an electrode member 3 placed on the proton conductive body 2 for oxidizing a carbon-containing component 5 in a gaseous mixture containing H2O 4 and a carbon-containing component 5.

[0064]The proton conductive body 2 has a conducting rate of 0.01 Scm−1or more at a temperature of 400° C. or less.

[0065]The electrode member 3 includes an anode electrode portion 31 and a cathode electrode portion 32 held in contact with each other. The electrode member 3 allows a proton (H+) to be separated from H2O 4 placed in contact with a boundary portion between the anode electrode portion 31 and the proton conductive body 2 to facilitate a reaction introducing the proton into the proton conductive body 2. Furthe...

second embodiment

[0082]With the present embodiment, three kinds of oxidizing devices are prepared in structures including the proton conductive bodies of the first embodiment containing compositions of TiP2O7, Ba Ce0.85Y0.15O3-α and La0.9Sr0.1Sc3-α, respectively.

[0083]The proton conductive bodies had electric conductivities of MP2O7 (M=Sn, Ti) (under a condition of 250° C., the electric conductivities can be described as 5.8×10−2 Scm−1>>BaCe0.85Y0.15O3-α (under a condition of 400° C., the electric conductivities can be described as 1.0×10−2 Scm−1)>>La0.9Sr0.1ScO3-α) (under a condition of 500° C., the electric conductivities can be described as 1.4×10−3 Scm−1) in this order.

[0084]Further, tests were conducted to evaluate generation start temperatures of generating active oxygen and the amounts of generated active oxygen in the same methods conducted in the tests of the first embodiment. Results are indicated in FIG. 3. For comparison purposes, tests were also conducted on oxidizing devices incorporat...

third embodiment

[0090]With the present embodiment, oxidizing devices are prepared using proton conductive bodies (Sn0.9In0.1P2O7 (under a condition of 250° C., the electric conductivity is 0.194 Scm−1) and Ti0.95Al0.5P2O7 (under a condition of 250° C., the electric conductivity is 0.181 Scm−1)) having improved electric conductivities by adding In and Al as dopants to metallic sites of SnP2O7 and TiP2O7 of the proton conductive bodies.

[0091]Further, tests were conducted to evaluate generation start temperatures of generating active oxygen and the amounts of generated active oxygen in the same methods conducted in be tests of the first embodiment. Results are indicated in FIG. 4. For comparison purposes, tests were also conducted on oxidizing devices employing SnP2O7 and only CB, respectively, with results being indicated in FIG. 4.

[0092]In FIG. 4, the abscissa axis indicates a temperature (° C.) and the ordinate axis indicates the amount (μmol / min) of generated CO2.

[0093]It turns out from FIG. 4 tha...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
temperatureaaaaaaaaaa
temperaturesaaaaaaaaaa
temperaturesaaaaaaaaaa
Login to View More

Abstract

An oxidizing device and an oxidizing method for oxidizing a carbon-containing component in a gaseous mixture containing H2O and the carbon-containing component are disclosed having a proton conductive body and an electrode member placed on the proton conductive body. The electrode member has an anode electrode and a cathode electrode held in contact with each other and the proton conductive body has electric conductivity of 0.01 Scm−1 or more at a temperature of 400° C. or less. The anode electrode separates a proton (H+) from H2O at a boundary portion between the anode electrode and the proton conductive body to facilitate a reaction to introduce the proton into the proton conductive body. The cathode electrode facilitates a reduction reaction in the presence of the proton supplied from the proton conductive body at a boundary portion between the cathode electrode and the proton conductive body.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This application is based on Japanese Patent Application No. 2008-85238, filed on Mar. 28, 2008, the content of which is hereby incorporated by reference.BACKGROUND OF THE INVENTION[0002]1. Technical Field of the Invention[0003]The present invention relates to oxidizing devices or more particularly, to an oxidizing device for oxidizing a carbon-containing component and a method of oxidizing the carbon-containing component.[0004]2. Description of the Related Art[0005]In the related art, attempts have heretofore been made to provide an exhaust gas purifying system as a catalyst converter system for purifying exhaust gases emitted from an internal combustion engine such as an automotive engine or the like. The exhaust gas purifying system incorporates therein an exhaust gas purifying catalyst body, located in an exhaust pipe of the internal combustion engine, which has a carrier (catalyst carrier) carrying thereon catalyst components. This c...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(United States)
IPC IPC(8): C25B3/02C25B9/00C25B1/02C25B3/23
CPCB01D2257/702B01D53/326
Inventor TERANISHI, SHINYAMIZUTANI, KEIGO
Owner NIPPON SOKEN
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More