Continuous collection method of particle component in aqueous solution and apparatus therefor

a technology of continuous particle component and aqueous solution, which is applied in the direction of solvent extraction, separation process, filtration treatment, etc., can solve the problems of increased running cost, increased maintenance cost, and difficult handling, and achieves more stable operation, finer grain, and stable operation

Inactive Publication Date: 2010-04-01
JAPAN ATOMIC ENERGY AGENCY INDEPENDANT ADMINISTRATIVE CORP
View PDF9 Cites 19 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0013]By adopting the counter-current method, emulsion flow can be more stabilized and more fine-grained in comparison with the apparatus based on the single current method. In addition, in the counter-current method in which the extracting solvent phase is fine-grained and circulated, the apparatus can be operated in stably without any effect by the particle component. This is realized by using such a characteristic that the particle component in the aqueous solution is never distributed into the extracting solvent. Thus, upon making the extracting solvent phase fine-grained, there is no need for paying attention to the plugging problem in the head part (the second head part). In the emulsion flow based on the counter-current method, it is proved that the structure of the second head part influences the quality of emulsion flow, and that the structure of the first head part spouting the aqueous phase is not dominant. This means that, even if the first head part may not have a structure in which the particle component cannot pass sufficiently through the head part (the structure in which the aqueous phase may not be fine-grained), there is no significant effect on the extractability. The invention of the emulsion flow has been completed according to those new findings.
[0014]It will be appreciated that the apparatus according to the

Problems solved by technology

The above mentioned apparatuses, however, have the common principle for mixing two liquid phases by applying mechanical external forces (such as stirring and vibrating) continuously or intermittently, which may lead to such disadvantageous aspects as being not easy to handle, increased running cost, increased maintenance cost, increased apparatus manufacturing cost (initial cost), uncertain safety features.
More specifically, they include: 1) large energy load required to generate mechanical external forces; 2) load and stress at the driving parts for generating mechanical external forces; 3) long adjusting work required to prepare and setup the operation of apparatus; 4) risk of ignition due to friction or static electricity at the driving parts; 5) high strength and high price materials required to manufacture the driving parts; 6) ambie

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Continuous collection method of particle component in aqueous solution and apparatus therefor
  • Continuous collection method of particle component in aqueous solution and apparatus therefor
  • Continuous collection method of particle component in aqueous solution and apparatus therefor

Examples

Experimental program
Comparison scheme
Effect test

embodiment 1

Experiment for Collecting Particle Component in Aqueous Solution by Small-sized Apparatus

[0047]Refer to FIG. 3A and FIG. 3B. Using a small-sized emulsion flow apparatus 10a (with the apparatus volume=3 litters and the apparatus weight=2 kg), an experiment for collecting aluminum oxide Al2O3 particles was carried out. More specifically, 20 litters of aqueous nitric acid solution (pH 2) including aluminum oxide Al2O3 particles (with particle diameter between 20 μm and 25 μm) by 0.02 M were prepared and an experiment for collecting the particle component was carried out by using a small-sized emulsion flow apparatus provided with 1 litter of isooctane. FIG. 3A shows a photo picture of the small-sized emulsion flow apparatus used in the experiment. The first head part 11 used in the apparatus has such a structure that the side wall of the hollow cylinder with its one end being closed, being made of polypropylene, is and being provided with 10 holes having 1 mm diameter. The second head ...

embodiment 2

Experiment for Collecting Particle Component in Aqueous Solution by Intermediate-sized Apparatus

[0049]Refer to FIG. 4A. FIG. 4A shows an intermediate-sized emulsion flow apparatus. The term of “Intermediate-sized” apparatus means an apparatus having an apparatus volume three times larger than the apparatus volume used in Embodiment 1. In this experiment, the intermediate-sized emulsion flow apparatus shown in FIG. 4A (with the apparatus volume=9 litters and the apparatus weight=4 kg) was used. The first head part 11 used in the apparatus has such a structure that the side wall of the hollow cylinder with its one end being closed, being made of polypropylene, and being provided with 6 holes having 4.8 mm diameter. The second head part 12 has such a structure that a sintered glass plate having pores with 40 μm diameter bonded onto the end of the hollow cylinder as described above. In order to avoid emulsion mixed phase and supply clean solvent phase, the upper phase separation part 14...

embodiment 3

Experiment for Collecting Simultaneously Particle Component and Dissolved Component in Aqueous Solution

[0053]Dissolved metallic ion and suspended particle component can be selectively and simultaneously collected by adding an extraction agent relevant to the metal ion to such a solvent phase as isooctane; while, in Embodiment 1 and Embodiment 2, pure isooctane is used. In Embodiment 3, an experiment was carried out by using the above described intermediate-sized emulsion flow apparatus provided with 2 litters of isooctane including bis(2-ethylhexyl) phosphoric acid (DEHPA) as the extraction agent by 1×10−3 M and with 200 litters of aqueous nitric acid solution (pH 2) including aluminum oxide Al2O3 particles as the particle component by 0.02 M and ytterbium Yb (trivalent ion) as the dissolved component by 6×10−6 M. As the experimental result, almost 100% of aluminum oxide Al2O3 particles as the particle component and about 98% of ytterbium Yb as the dissolved component could be separ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The particle components may be collected by using a phenomenon that the particle components in the aqueous phase aggregate at the liquid-to-liquid interface. Both of the particle components and the dissolved components in the aqueous phase may be simultaneously collected if combined with liquid-liquid extraction phenomenon that the dissolved components in the aqueous phase are collected into the solvent phase through the liquid-to-liquid interface. The aggregation phenomenon of the particle components at the liquid-to-liquid interface may be promoted by using an emulsion flow method, a method of applying mechanical external forces (such as stirring and vibrating) or another method combining both the above-mentioned methods.

Description

BACKGROUND OF THE INVENTION[0001]The present invention relates to a method for collecting continuously particle component in the aqueous solution without using filters and / or centrifuge separators. The method utilizes a phenomenon that particle component in the aqueous solution aggregates at the liquid-to-liquid interface between the aqueous solution (aqueous phase) containing the particle component as the target component and the solvent (solvent phase) having hydrophobic nature and not mixing with water.[0002]Liquid-liquid extraction method (solvent extraction method), by which the target component included in the aqueous solution may be extracted into the solvent (such as organic solvent) that contains extraction agents (extractants) having hydrophobic nature and does not mix with water, is widely used in various industrial fields such as metal refinement, nuclear fuel reprocessing, removal of harmful ingredients in the waste water, recycling by separation and recovering of comme...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): B01D15/32B01D15/08
CPCB01D11/0434B01D11/0438C02F1/54C02F1/26C02F1/001
Inventor NAGANAWA, HIROCHIKAYANASE, NOBUYUKINAGANO, TETSUSHI
Owner JAPAN ATOMIC ENERGY AGENCY INDEPENDANT ADMINISTRATIVE CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products