Multicomponent fibers and microdenier fabrics prepared by fibrillation thereof

a technology of microdenier fabrics and fibers, which is applied in the direction of needling machines, weaving, transportation and packaging, etc., can solve the problems of poor fabric formation, unfavorable production of nonwoven elastomers where the elastomer is exposed, and remains tacky, so as to reduce the difficulty of spinning

Inactive Publication Date: 2012-09-13
NORTH CAROLINA STATE UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This is partly because the elastomers do not solidify, crystallize rapidly, and remain tacky.
Thus, during extrusion, the elastomers tend to stick together and form bundles, which results in poor fabric formation.
To date, spunbonded elastomers where the elastomer is exposed have not been produced successfully in nonwovens.
However, high concentrations of additives within the polymer can result in fibers breaking during extrusion.
In bicomponent fibers, such additives have previously been added to the core or the sheath in small quantities, but in splittable fibers, the addition of such additives typically results in fiber breakage during extrusion.
Consequently, if the components selected do not have properties which are closely analogous, the continuous fiber may suffer defects during manufacturing such as breaking or crimping.
Such defects would render the filament unsuitable for further processing.
This fiber is anisotropic and is difficult to process as a staple fiber, but can work as a continuous filament.
Another disadvantage utilizing segmented pie configurations is that the overall fiber shape upon splitting is a wedge shape.
Such shapes are currently unavailable under standard segmented processes.
Accordingly, when manufacturing microdenier fibers utilizing the segmented pie format, certain limitations are placed upon the selection of materials.
If the materials are too dissimilar, the fibers will break during processing.
Such a process is not environmentally friendly as an alkali solution is often utilized, which may require wastewater treatment.
Additionally, since it is necessary to expose the island components to the solvent that dissolves the sea, this method restricts the types of polymers which may be utilized as islands to those not affected by the solvent that dissolves the sea.
In summary, what has been accomplished so far has limited application because of the limitations posed by the choice of the polymers that would allow ease of spinning and splittability for segmented fibers.
The spinning is problematic because both polymers are exposed on the surface and therefore, variations in elongational viscosity, quench behavior, and relaxation cause anisotropies that lead to spinning challenges.
Furthermore, the incorporation of elastomer-containing components and additive-containing polymeric components within the fibers has been problematic.
When a fiber contains additive-containing polymeric components, the additive concentration within the fiber is limited due to the likelihood of fiber breakage during extrusion.
Still further, a major limitation of the current art is that the fibers form wedges and there is no flexibility with respect to fiber cross sections that can be achieved.
However, with the requirement of removing the sea, limitations exist due to limited availability of suitable polymers for the sea and island components.
Prior to the inventive activity set forth in the related patent applications, islands in the sea technology has not been employed for making microdenier fibers other than via the removal of the sea component because of the common belief that the energy required to separate the islands from the sea renders this process commercially unviable.

Method used

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  • Multicomponent fibers and microdenier fabrics prepared by fibrillation thereof
  • Multicomponent fibers and microdenier fabrics prepared by fibrillation thereof
  • Multicomponent fibers and microdenier fabrics prepared by fibrillation thereof

Examples

Experimental program
Comparison scheme
Effect test

example 1

Elastomeric Example with Permanent Stretch and Recovery

[0069]These samples were made with the cross section in FIG. 7A, where the elastomer (a styrene / isoprene copolymer) was component 24 and components 14 and 22 were selected from nylon 6 for one example and polyester (polyethylene terephthalate with an intrinsic viscosity of 0.56—Eastman Chemical) for the other. The ratios were selected to be 20% by volume elastomer and 80% by volume nylon or polyester. One example was also run with a 50 / 50 ratio for the two polymers.

[0070]Elasticity (stretch and recovery) in the fabrics was achieved by spinning the fibers using the noted cross-section, collecting the fibers on an open mesh belt and using a water jet to break up and entangle the fibers. The method used to prepare the fabrics may affect the openness of the fabric structure. The open structure can be affected by the openness of the collecting belt (e.g. a 14 mesh belt was used for the nylon samples and a 40 mesh was used for the pol...

example 2

Effect of Structure on Unidirectional Stretch and Recovery

[0082]An additional set of fabrics was produced and tested for the effect of structure on unidirectional properties of the fabric with respect to stretch and recovery. The fabrics tested include a 75% PET / 25% elastomer material, a 75% PA6 / 25% elastomer material, and a 50% PA6 / 50% elastomer material. The polymers used in these materials were the same as those used in the previous examples (elastomer=Kraton styrene and isoprene block copolymer, PET=polyethylene terephthalate with an intrinsic viscosity of 0.56 from Eastman Chemical, PA6=polyamide 6 from BASF with a viscosity of 2.7).

[0083]The results of this additional study are summarized below in Table 9. The weights chosen were 100 and 150 g / m2. These were entangled using a 100 mesh stainless steel mesh belt, and some samples were further entangled using an open mesh (14 or 20) polymer belt, as indicated below. The samples were tested according to ASTM test method for Stretc...

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Abstract

Multicomponent fibers and fabrics made therefrom are provided. The fibers include a multilobal sheath fiber component surrounding a core fiber component, wherein the fibers can be fibrillated to provide a plurality of intertwined microdenier fiber components. Methods of providing such fabrics are also disclosed.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is a continuation of U.S. application Ser. No. 12 / 543,636, filed Aug. 19, 2009, which is a continuation-in-part of U.S. application Ser. No. 11 / 769,871, filed Jun. 28, 2007, which is a continuation-in-part of U.S. application Ser. No. 11 / 473,534, filed Jun. 23, 2006, which claims priority to U.S. Prov. Appl. Ser. No. 60 / 694,121, filed Jun. 24, 2005, all of which are incorporated herein by reference in their entireties.FIELD OF THE INVENTION[0002]The invention relates generally to the manufacture of microdenier fibers and nonwoven products manufactured from such fibers. The fibers may contain one or more elastomers and / or particulate additives.BACKGROUND OF THE INVENTION[0003]Nonwoven spunbonded fabrics are used in many applications requiring a lightweight disposable fabric. Therefore, most spunbonded fabrics are designed for single use and are designed to have adequate properties for the applications for which they are in...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): D04H3/018D02G3/32D04H5/02D02G3/36
CPCD01D5/0985D01D5/253D01D5/34D01D5/423D01F8/06Y10T428/2929D01F8/14D04H1/465D04H3/102D04H3/16D01F8/12D04H1/49D04H3/105D04H3/11D04H3/14Y10T442/612Y10T442/621Y10T442/611Y10T442/602
Inventor POURDEYHIMI, BEHNAMSHARP, STEPHEN R.
Owner NORTH CAROLINA STATE UNIV
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