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Process for the production of a dark-color multi-layer coating

a multi-layer coating and production process technology, applied in coatings, electrostatic spraying apparatuses, special surfaces, etc., can solve the problems of undesirable heating types, and achieve the effect of low heat development in sunligh

Active Publication Date: 2012-10-25
AXALTA COATING SYST IP CO LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0016]Apart from the pigmentation of both coating compositions A and B, it is also essential in the practice of the present process that coating composition A comprises at least one component selected from the group consisting of components (i) to (v) and that coating composition comprises at least one component selected from the group consisting of components (i′) to (v′). It has been found that the presence of at least one component selected from the group consisting of components (i) to (v) in coating composition A and of at least one component selected from the group consisting of components (i′) to (v′) in coating composition B allows to achieve both, the desired dark-color shade of the multi-layer coating and the desired low heat development in sunlight, although coating compositions A and B and the clear coat composition are applied wet-on-wet-on-wet.
[0019]As already mentioned, the process of the present invention allows to achieve both, the desired dark-color shade and the low heat development in sunlight, although coating compositions A and B and the clear coat composition are applied wet-on-wet-on-wet. The desired dark-color shade and the low heat development in sunlight can even be achieved when the wet-on-wet-on-wet coating process is carried out in the context of an industrial mass production coating process, i.e., in an industrial painting facility which allows only for short time intervals between the three paint application steps. The short time-intervals between the three paint application steps result from the fact that the substrates to be coated are moving along a continuously moving painting line.

Problems solved by technology

This type of heating is often undesirable; for example, it may be undesirable for the actual substrate material itself and / or for the interior of the substrate to be heated up.

Method used

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Examples

Experimental program
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Effect test

examples

[0109]Unless otherwise noted, all components of the following examples are believed to be available from the Aldrich Chemical Company, Milwaukee, Wis. The following other components were used in the examples.

[0110]CYMEL® 1168, melamine formaldehyde resin available from Cytec Industries Inc. West Patterson, N.J.

[0111]High solids acrylic polymer, as disclosed in US 2008 / 0131607 A1, page 8, Acrylic Polymer #4.

[0112]Dispersant #1, as disclosed in U.S. Pat. No. 6,472,463 B1, Example 6.

[0113]Dispersant #2, as disclosed in U.S. Pat. No. 6,472,463 B1, Example 8.

[0114]Microgel resin, as disclosed in US 2008 / 0131607 A1, example on pages 8-9.

[0115]Nacure® XP 221, sulphonic acid catalyst available from King Industries Norwalk, Conn.

[0116]PALIOGEN® BLACK L 0086, perylene black pigment available from BASF, Germany.

[0117]RAVEN 5000®, carbon black pigment available from Columbia Chemical Co., Marietta, Ga.

[0118]GARAMITE 2578®, sheet silicate available from Southern Clay Products, Gonzales, Tex.

[011...

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Abstract

A process for the production of a dark-color multi-layer coating, comprising the successive steps:(1) applying an NIR-opaque coating layer A′ from a solventborne coating composition A to a substrate,(2) applying a coating layer B′ from a solventborne coating composition B onto the substrate provided with coating layer A′,(3) subjecting the coated substrate obtained in step (2) to a drying step,(4) applying a clear coat layer, and(5) curing the coating layers simultaneously;wherein both coating compositions A and B comprise binders and crosslinkers comprising melamine-formaldehyde resin crosslinker,wherein both coating compositions A and B comprise certain proportions of cellulose ester binder and NAD binder and / or sheet silicate and / or fumed silica and / or urea SCA and / or polyolefine wax,wherein the pigment content of coating composition A consists 90 to 100 wt. % of aluminum flake pigment and 0 to 10 wt. % of further pigment,wherein the pigment content of coating composition B consists 50 to 100 wt. % of black pigment with low NIR absorption and 0 to 50 wt. % of further pigment.

Description

FIELD OF THE INVENTION [0001]The invention is directed to a process for the production of a dark-color multi-layer coating.DESCRIPTION OF THE PRIOR ART[0002]Dark-color coatings often contain carbon black pigments which absorb radiation in the near-infrared wavelength range and transform it into heat. Substrates coated with paint coatings of this type heat up in the NIR-containing sunlight; this occurs via heat conduction, i.e., heat is directly transferred to the substrate from the coating layer containing carbon black pigments and heated by solar radiation. This type of heating is often undesirable; for example, it may be undesirable for the actual substrate material itself and / or for the interior of the substrate to be heated up. Motor vehicles are probably the most prominent examples of substrates which comprise an interior. Vehicles with light-color coatings do not heat up as much and less fuel is required to operate the vehicle air-conditioning system than in corresponding mode...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B05D5/06
CPCB05D7/14B05D7/572B05D1/02B05D7/16B05D5/06
Inventor DOESSEL, KARL-FRIEDRICHRICHTER, GUNTER
Owner AXALTA COATING SYST IP CO LLC