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Nonaqueous electrolyte secondary battery insulating porous layer and nonaqueous electrolyte secondary battery laminated separator

a secondary battery and nonaqueous electrolyte technology, applied in the direction of batteries, cell components, electrical equipment, etc., can solve the problems of internal short circuit or external short circuit, intense heat generation, etc., and achieve the effect of improving discharge output characteristic and discharge output characteristi

Active Publication Date: 2017-06-01
SUMITOMO CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a nonaqueous electrolyte secondary battery separator and nonaqueous electrolyte secondary battery laminated separator that can improve the discharge output characteristic of a nonaqueous electrolyte secondary battery. This results in a superior discharge output characteristic compared to conventional nonaqueous electrolyte secondary batteries.

Problems solved by technology

Nonaqueous electrolyte secondary batteries let a large current flow and thus generate intense heat in the event of an accident such as a breakage of the battery or a breakage of the device using the battery has caused an internal short circuit or external short circuit.

Method used

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  • Nonaqueous electrolyte secondary battery insulating porous layer and nonaqueous electrolyte secondary battery laminated separator

Examples

Experimental program
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Effect test

embodiment 2

Embodiment 1: Nonaqueous Electrolyte Secondary Battery Insulating Porous Layer and Nonaqueous Electrolyte Secondary Battery Laminated Separator

[0026]Embodiment 1 of the present invention is a nonaqueous electrolyte secondary battery insulating porous layer containing fine particles of a metal salt, the metal salt having a Lewis acid peak area within a range of not less than 0.2 g−1 and not more than 3.6 g−1 per unit weight, the Lewis acid peak area being measured by an infrared spectroscopy-based acid nature evaluation method for a solid surface.

[0027]Embodiment 2 of the present invention is a nonaqueous electrolyte secondary battery laminated separator including: a porous film containing a polyolefin as a main component; and an insulating porous layer disposed on one or both surfaces of the porous film, the insulating porous layer containing fine particles of a metal salt, the metal salt having a Lewis acid peak area within a range of not less than 0.2 g−1 and not more than 3.6 g−...

embodiment 4

Embodiment 3: Nonaqueous Electrolyte Secondary Battery Member and Nonaqueous Electrolyte Secondary Battery

[0100]Embodiment 3 of the present invention may be a nonaqueous electrolyte secondary battery member including a cathode, the insulating porous layer as Embodiment 1 of the present invention, and an anode, the cathode, the porous layer, and the anode being arranged in that order. Embodiment 3 of the present invention may alternatively be a nonaqueous electrolyte secondary battery member including a cathode, the nonaqueous electrolyte secondary battery laminated separator as Embodiment 2 of the present invention, and an anode, the cathode, the nonaqueous electrolyte secondary battery laminated separator, and the anode being arranged in that order.

[0101]A nonaqueous electrolyte secondary battery member of an embodiment of the present invention includes, as a separator or a separator member, an insulating porous layer containing fine metal salt particles having, per unit weight, a...

example 1

[0146]

[0147]A porous film as a base material was prepared from polyethylene (polyolefin).

[0148]Specifically, 70 parts by weight of an ultra-high-molecular-weight polyethylene powder (340M [produced by Mitsui Chemicals, Inc.]) and 30 parts by weight of a polyethylene wax having a weight-average molecular weight of 1000 (FMP-0115 [produced by Nippon Seiro Co., Ltd.]) were mixed with each other to prepare mixed polyethylene. To 100 parts by weight of the mixed polyethylene prepared, 0.4 parts by weight of an antioxidant (Irg1010 [produced by CIBA Specialty Chemicals Inc.]), 0.1 parts by weight of another antioxidant (P168 [produced by CIBA Specialty Chemicals Inc.]), and 1.3 parts by weight of sodium stearate were added, and calcium carbonate having an average particle diameter of 0.1 μm (produced by Maruo Calcium Co., Ltd.) was further added to have a proportion of 38% by volume with respect to the total volume. This composition was mixed in a Henschel mixer in the form of powder, and...

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Abstract

Provided as a nonaqueous electrolyte secondary battery insulating porous layer that allows a nonaqueous electrolyte secondary battery to have an improved discharge output characteristic is a nonaqueous electrolyte secondary battery insulating porous layer containing fine particles of a metal salt having a Lewis acid peak area within a range of not less than 0.2 g−1 and not more than 3.6 g−1 per unit weight, the Lewis acid peak area being measured by an infrared spectroscopy-based acid nature evaluation method for a solid surface, the Lewis acid peak area of a metal salt per unit weight being defined as a value resulting from dividing (i) the area of a peak present in a region of 1447 cm−3 to 1460 cm−1 of an infrared absorption spectrum measured of a sample on which pyridine was adsorbed and from which the pyridine has then been desorbed by (ii) the weight of the metal salt.

Description

[0001]This Nonprovisional application claims priority under 35 U.S.C. §119 on Patent Application No. 2015-232154 filed in Japan on Nov. 27, 2015, the entire contents of which are hereby incorporated by reference.TECHNICAL FIELD[0002]The present invention relates to an insulating porous layer for a nonaqueous electrolyte secondary battery (hereinafter referred to as “nonaqueous electrolyte secondary battery insulating porous layer”) and a laminated separator for a nonaqueous electrolyte secondary battery (hereinafter referred to as “nonaqueous electrolyte secondary battery laminated separator”).BACKGROUND ART[0003]Nonaqueous electrolyte secondary batteries, particularly lithium secondary batteries, have high energy density and are thus in wide use as batteries for personal computers, mobile telephones, portable information terminals, and the like.[0004]Nonaqueous electrolyte secondary batteries, typically lithium secondary batteries, have high energy density. Nonaqueous electrolyte s...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): H01M2/16H01M50/414H01M50/431H01M50/443H01M50/451H01M50/489
CPCH01M2/166H01M2220/30H01M2/1686H01M10/0525H01M50/446H01M50/451H01M50/431H01M50/443H01M50/489H01M50/414Y02E60/10H01M50/46H01M50/449
Inventor ARISE, ICHIROMURAKAMI, CHIKARA
Owner SUMITOMO CHEM CO LTD