Nonaqueous electrolyte secondary battery insulating porous layer and nonaqueous electrolyte secondary battery laminated separator
a secondary battery and nonaqueous electrolyte technology, applied in the direction of batteries, cell components, electrical equipment, etc., can solve the problems of internal short circuit or external short circuit, intense heat generation, etc., and achieve the effect of improving discharge output characteristic and discharge output characteristi
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embodiment 2
Embodiment 1: Nonaqueous Electrolyte Secondary Battery Insulating Porous Layer and Nonaqueous Electrolyte Secondary Battery Laminated Separator
[0026]Embodiment 1 of the present invention is a nonaqueous electrolyte secondary battery insulating porous layer containing fine particles of a metal salt, the metal salt having a Lewis acid peak area within a range of not less than 0.2 g−1 and not more than 3.6 g−1 per unit weight, the Lewis acid peak area being measured by an infrared spectroscopy-based acid nature evaluation method for a solid surface.
[0027]Embodiment 2 of the present invention is a nonaqueous electrolyte secondary battery laminated separator including: a porous film containing a polyolefin as a main component; and an insulating porous layer disposed on one or both surfaces of the porous film, the insulating porous layer containing fine particles of a metal salt, the metal salt having a Lewis acid peak area within a range of not less than 0.2 g−1 and not more than 3.6 g−...
embodiment 4
Embodiment 3: Nonaqueous Electrolyte Secondary Battery Member and Nonaqueous Electrolyte Secondary Battery
[0100]Embodiment 3 of the present invention may be a nonaqueous electrolyte secondary battery member including a cathode, the insulating porous layer as Embodiment 1 of the present invention, and an anode, the cathode, the porous layer, and the anode being arranged in that order. Embodiment 3 of the present invention may alternatively be a nonaqueous electrolyte secondary battery member including a cathode, the nonaqueous electrolyte secondary battery laminated separator as Embodiment 2 of the present invention, and an anode, the cathode, the nonaqueous electrolyte secondary battery laminated separator, and the anode being arranged in that order.
[0101]A nonaqueous electrolyte secondary battery member of an embodiment of the present invention includes, as a separator or a separator member, an insulating porous layer containing fine metal salt particles having, per unit weight, a...
example 1
[0146]
[0147]A porous film as a base material was prepared from polyethylene (polyolefin).
[0148]Specifically, 70 parts by weight of an ultra-high-molecular-weight polyethylene powder (340M [produced by Mitsui Chemicals, Inc.]) and 30 parts by weight of a polyethylene wax having a weight-average molecular weight of 1000 (FMP-0115 [produced by Nippon Seiro Co., Ltd.]) were mixed with each other to prepare mixed polyethylene. To 100 parts by weight of the mixed polyethylene prepared, 0.4 parts by weight of an antioxidant (Irg1010 [produced by CIBA Specialty Chemicals Inc.]), 0.1 parts by weight of another antioxidant (P168 [produced by CIBA Specialty Chemicals Inc.]), and 1.3 parts by weight of sodium stearate were added, and calcium carbonate having an average particle diameter of 0.1 μm (produced by Maruo Calcium Co., Ltd.) was further added to have a proportion of 38% by volume with respect to the total volume. This composition was mixed in a Henschel mixer in the form of powder, and...
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