The invention discloses a composite
molecular sieve film based on paper-shaped gradient
metal microfibers as well as a preparation method and an application thereof. The preparation method of the composite
molecular sieve film comprises the steps of dosing a tackiness agent, a
metal fibre and water according to the weight ratio at 1 to (1-3) to (100-500), utilizing a wet method paper technology to prepare a front driving body,
sintering to prepare a paper-shaped
sintering metal microfiber carrier with a three-dimensional
network structure, utilizing a NaOH water solution and a H2SO4 water solution to soak, and
sintering so as to obtaining the carrier; utilizing cetyl trimethyl
ammonium bromide, ethyl
orthosilicate and
ammonium hydroxide to prepare a
seed crystal; enabling a
seed crystal solution to dissolve in an
ethanol solution so as to obtain a
molecular sieve powder impregnation liquid, putting the carrier into the molecular
sieve powder impregnation liquid to soak,
drying so as to obtain the paper-shaped sintering metal
microfiber carrier of a pre-planting
plant; washing and calcining a product after
secondary growth so as to obtain the paper-shaped gradient metal
microfiber composite molecular
sieve film. The composite molecular
sieve film provided by the invention has the advantages of being continuously compact, adjustable in thickness, applicable tp the wet-type
catalytic oxidation of phenolic
wastewater, and high in reaction efficiency.