The invention discloses pain relieving baijiu. The pain relieving baijiu is prepared from, by weight, 1-1.5 parts of tangerine peels, 4-5 parts of licorice roots, 2-4 parts of radix peucedani, 0.4-0.6 part of a notopterygium root, 1-2 parts of typhonium giganteum, 1-2 parts of alangium platanifolium, 1-1.5 parts of stauntonia latifolia, 4-5 parts of dried rehmannia roots, 2-4 parts of red dates, 0.4-0.6 part of longan pulp, 1-5 parts of peeled cinnamon, 1-2 parts of honey-fried licorice roots, 2-4 parts of radix aconiti preparata and the balance baijiu. According to the pain relieving baijiu, purely-natural plant materials are adopted, the cost of the raw materials is reasonable, the taste is excellent, side effects are avoided, and the health-care effects of dispelling disease, keeping health, replenishing blood and the like are obvious; the production cost of common medicine baijiu is greatly reduced, and the convenience is provided for medicine-baijiu health-care lives of common crowds.