Optical compensating sheet, polarizing plate and liquid crystal display device
An optical compensation sheet and polarizing plate technology, which is applied in the field of optical compensation sheets, can solve the problems of reduced intensity, deterioration of optical properties, and incomplete research on existing technologies.
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[0348] Next, a method for producing a thin film using a coating liquid in the present invention will be described. The preparation method and equipment of the polymer film can use the currently known solution casting film forming method and solution casting film forming device called the cylinder method or the conveyor belt method for the preparation of the polymer film.
[0349] The film forming process will be described. The coating solution (cellulose acylate solution) prepared in the dissolver (tank) is temporarily stored in the storage tank, and the final preparation is performed to defoam the coating solution containing air bubbles. It is important to remove aggregates and foreign matter by precise filtration of the prepared coating liquid. Specifically, it is preferable to use a filter having a pore size as small as possible within a range in which components in the coating liquid are not removed. Filtration uses a filter with an absolute filtration precision of 0.1 to...
Embodiment 1
[0727] (Manufacture of cellulose acylate film)
[0728]The following composition was put into the mixing tank, and it stirred, heating, and each component was dissolved, and the cellulose acylate solution was prepared.
[0729]
[0730] In another mixing tank, 16 parts by mass of the following delayed rising agent, 80 parts by mass of methylene chloride, and 20 parts by mass of methanol were charged and stirred while heating to prepare a delayed rising agent solution.
[0731] delayed ascension agent
[0732]
[0733] 474 parts by mass of the cellulose acylate solution and 25 parts by mass of the delayed ascension agent solution were mixed and fully stirred to prepare a coating solution. The added amount of the delayed rise agent was 3.5 parts by mass relative to 100 parts by mass of cellulose acetate.
[0734] The obtained coating solution is cast with a cylindrical casting machine. When the film surface temperature on the cylinder reaches 40°C, dry it with hot air at...
Embodiment 2
[0749] (Manufacture of cellulose acylate film)
[0750] The following composition was put into the mixing tank, and it stirred, heating, and each component was dissolved, and the cellulose acylate solution was prepared.
[0751]
[0752] In another mixing tank, 16 parts by mass of the delayed rising agent used in Example 1, 80 parts by mass of methylene chloride, and 20 parts by mass of methanol were charged, stirred while heating, and a delayed rising agent solution was prepared.
[0753] 484 parts by mass of the cellulose acylate solution and 15 parts by mass of the delayed rising agent solution were mixed and stirred sufficiently to prepare a coating liquid. The added amount of the delayed rising agent was 2.0 parts by mass relative to 100 parts by mass of cellulose acetate.
[0754] The obtained coating solution is cast with a cylinder casting machine. When the temperature of the film surface on the cylinder reaches 40°C, it is dried with hot air at 65°C for 1 minute, ...
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