Glass fiber with low permittivity

A low dielectric constant, glass fiber technology, applied in the field of glass fiber with low dielectric constant, can solve the problems of high dielectric constant, poor water resistance, peeling, etc., achieve good water erosion resistance, excellent dielectric properties, reduce harshness effect

Active Publication Date: 2007-08-08
TAISHAN FIBERGLASS INC
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

[0009] In response to these situations, a lot of research has been done at home and abroad, and some patents have also appeared, but some of them are not easy to operate in actual production, and some are not suitable for the actual domestic materials.
D glass has a lower dielectric constant and can reduce the dielectric constant of the foil-clad board, but due to its poor melting, it is easy to produce veins and bubbles, and there are many broken glass fibers in the spinning process. At the same time, due to its aluminum content If it is too low, the water resistance is very poor, so it is easy to cause the resin to peel off from it, so that the stable requirements of the process cannot be met when printing the wiring board
Although E glass has good water erosion resistance, its dielectric constant is relatively large, and its dielectric properties can no longer meet the requirements of the development of the electronics industry.
The glass fiber component with low dielectric constant introduced in U.S. Patent 6,846,761 has a dielectric constant of about 5.0, and there is still a considerable gap between its dielectric constant and D glass; the patent 02810477.3 applied by Saint-Gobain Vitrotes Co., Ltd. in France is introduced A new low dielectric constant glass fiber composition was developed, which uses P2O5 as an essential component, so that its dielectric loss at high frequency (10GHz) is significantly lower than that at lower frequencies, However, the dielectric constant does not change significantly at high or low frequencies, and is still around 5.0; the low-dielectric glass fiber dielectric constant introduced by Nippon Textile Co., Ltd.'s patent 96194439.0 is 4.2-4.8, which fails to reach below 4.2. There will still be high dielectric loss during use. At the same time, when the corresponding components described in the specification are tested and melted during the research process, the obtained glass does not obtain the usability and process performance described in the patent.

Method used

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Embodiment Construction

[0029] The technical solution of the present invention is further illustrated by the following examples listed in Table 1, and these examples are only further illustrations and not limitations thereto.

[0030] Where the total content of components is slightly larger or greater than 100%, it can be understood that the residual content is caused by impurities and a small amount of components that cannot be analyzed, or by an acceptable approximation in the analytical method used.

[0031] T(logη=3) means that the glass liquid viscosity is 10 3 The temperature of the molten glass (suitable drawing temperature).

[0032] The devitrification upper limit temperature refers to the upper limit of the temperature at which the glass liquid is kept warm for a long time without crystallization or phase separation, which will cause the glass to devitrify. That is, if the molten glass is kept above this temperature for a long time (longer than the residence time of the molten glass in the...

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Abstract

The invention discloses a low-dielectric constant glass fiber, which comprises the following parts: 50- 60% SiO2, 6.0-9.5% Al2O3, 30.5-35% B2O3, 0-1.5% Na2O, 0-1.5% K2O, 0-1.5% Li2O, 0-5% CaO, 0-5% MgO, 0.5-2.5% ZnO, 0.5-5% TiO2. When the frequency is 1MHz under indoor temperature, the dielectric constant is 3.9-4.4, which is fit for high-density wiring circuit board.

Description

technical field [0001] The present invention relates to a glass fiber with low dielectric constant. technical background [0002] With the rapid development of information technology, the processing speed of electrical signals in electronic products and their accessories has been greatly improved. Electrical performance has become one of the factors restricting the development of information technology. At the same time, the continuous progress of radar technology requires the corresponding radome to have better wave permeability, which requires the materials used to have low dielectric constant and low dielectric loss. [0003] Printed circuit boards are mainly composed of reinforcement materials (now mainly electronic grade glass fibers) and resins. Various wires and electronic components are arranged on the board. [0004] In high-frequency lines, the signal propagation speed has the following relationship: [0005] V=K·C / sqrt(ε) [0006] In the formula: V-signal pro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C13/02C03C3/093
CPCC03C13/00C03C3/091C03C3/093
Inventor 张志法刘颖岳云龙邹仁贵李永艳许士国王丽英徐言超邵胜利宋晓于晓杰
Owner TAISHAN FIBERGLASS INC
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