Catalyzer slurry for producing fuel cell membrane electrode and process for production thereof

A fuel cell membrane and catalyst slurry technology, which is applied to fuel cell parts, battery electrodes, solid electrolyte fuel cells, etc., can solve problems such as troublesome, high operating environment requirements, and affecting battery electrode performance

Inactive Publication Date: 2008-01-02
SHANGHAI PEARL HYDROGEN POWER SOURCE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the solution is added to the catalyst alone for stirring and mixing, the catalyst and Nafion in the prepared catalyst slurry cannot be effectively dispersed and combined, which will affect its direct coating on the membrane to prepare CCM fuel cell components, thus affecting the electrode performance of the battery
[0007] Time-consuming, energy-intensive, and cumbersome methods of solvent exchange using Nafion / water-alcohol solutions
Moreover, most of the solvents are organic solvents, which are relatively toxic and require relatively high operating environments.

Method used

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  • Catalyzer slurry for producing fuel cell membrane electrode and process for production thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Get the HP40%Pt / C catalyst that 0.1g E-TEK company produces, add 2g acetic acid, ultrasonic vibration 5min, add the Nafion DE 520 dispersion liquid that Dupont company produces (wherein the concentration of perfluorosulfonic acid resin in the dispersion liquid is 5.4%, The solvent contains 45-48% of water, 45-48% of 1-propanol, less than 4% of ethylene glycol, and less than 1% of mixed ethers) 0.8g, ultrasonically oscillated for 5 minutes, and kept stirring. That is, a catalyst slurry of the present invention is obtained.

Embodiment 2

[0027] Mix 1g of perfluorosulfonic acid resin, 4g of water and 5g of ethanol, put it into an autoclave, seal it, heat it to 250 degrees Celsius, and keep stirring for 3 hours. After cooling, the dispersion liquid of the high molecular polymer proton conductor is obtained;

[0028] Take 0.1g of HP40%Pt / C produced by E-TEK Company, add 1g of oxalic acid, ultrasonically shake for 5min, add 0.5g of the above dispersion, ultrasonically shake for 5min, and keep stirring. That is, a catalyst slurry of the present invention is obtained.

Embodiment 3

[0030] Mix 1 g of sulfonated trifluorostyrene resin, 3 g of water and 6 g of 1-propanol, put into an autoclave, seal, heat, and keep stirring for 3 hours, and after cooling, the dispersion liquid of the high molecular polymer proton conductor is obtained;

[0031] Take 0.1g of HP40%Pt / C produced by E-TEK Company, add 3g of oxalic acid, ultrasonically shake for 5min, add 0.6g of the above dispersion, ultrasonically shake for 5min, and keep stirring. That is, a catalyst slurry of the present invention is obtained.

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PUM

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Abstract

A catalyst slurry for producing membrane electrode of fuel battery contains 1-40%wt solid catalyst particles, 1-40%wt macromolecule polyester conductor, 0.1-50%wt water, 1-50%wt alcohol, and 1-90%wt organic acid. And the relative preparation comprises that preparing the disperser of macromolecule polyester atom conductor and preparing catalyst slurry. The electrode made from the inventive catalyst slurry has better property than prior art, with easy preparation, saved time, saved force, and low energy consumption.

Description

technical field [0001] The invention relates to a catalyst and a preparation method thereof, in particular to a catalyst slurry for making fuel cell membrane electrodes and a preparation method thereof. Background technique [0002] The catalyst coating on the fuel cell membrane electrode is made by dispersing the solid particle catalyst in a solvent to make a catalyst slurry, and then coating the slurry on the proton exchange membrane, and then drying it to form a membrane. The performance of the catalyst slurry directly affects the performance of the manufactured membrane electrode, and ultimately affects the power generation performance of the fuel cell. [0003] A kind of catalyst slurry is provided in European patent EP 0955687 A2, mainly is that the Nafion alcohol aqueous solution that U.S. Dupont Company produces is added MOH, and H + Form Nafion solution becomes M + Type, then use high boiling point polar solvent to evaporate and replace the Nafion alcohol aqueous ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/86H01M8/02H01M8/10H01M4/88
CPCH01M4/8605Y02E60/50H01M4/8828
Inventor 田丙伦
Owner SHANGHAI PEARL HYDROGEN POWER SOURCE TECH
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