Oxidation continuous deferrization process for copper cobalt liquor

A solution, copper-cobalt technology, applied in the field of continuous iron removal by oxidation of copper-cobalt solution, can solve the problems of inability to realize continuous input and output of materials, increase production cost and labor intensity, reduce effective utilization of equipment, etc., and achieve iron removal Good effect, automatic control, quantity reduction effect

Inactive Publication Date: 2008-02-06
ZHEJIANG HUAYOU COBALT
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Problems solved by technology

[0002] The current iron removal method of copper-cobalt ore leaching solution adopts intermittent iron removal method. The so-called intermittent iron removal means that the iron-containing copper-cobalt solution completes a series of reaction processes such as oxidation and neutralization in a single iron removal tank. Finally, all the materials in the iron removal tank must be transferred out at one time before they can be fed into production again. The above-mentioned intermittent iron removal method cannot realize the continuous input and output of materials, resulting in a long turnaround time for materials between equipment, reducing the The effective utilization rate of equipment, the number of equipment used is large, but also increases the production cost and labor intensity

Method used

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Embodiment Construction

[0014] The material is copper-cobalt mineral acid solution, its composition is: 2g / L of ferrous iron, 1g / L of copper, 20g / L of cobalt, and the pH value is between 0.5-2.8.

[0015] The multi-stage continuous iron removal system used is composed of eight iron removal tanks in series. The iron-containing copper-cobalt solution is combined with the oxidant hydrogen peroxide to form a mixed solution before being added to the multi-stage continuous iron removal system. In the first iron removal tank Add the mixed solution, the Fe in the copper-cobalt solution 2+ fully oxidized to Fe 3+ , to judge Fe 2+ Whether it is completely oxidized, do a drop test with potassium ferricyanide, if there is no blue precipitate, it means Fe 2+ It has been completely oxidized, and the oxidized copper-cobalt solution flows from the previous tank to the next tank through the drop of the pipeline interface between the tanks, and then adds Na with a concentration of 7% to 8% from the third iron remova...

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Abstract

The present invention discloses an oxidation de-ironing method of copper cobalt solution. The iron removal of the copper cobalt ores lixivium adopts the interrupted de-ironing method, which can not realize the continuous input and output of material, thereby causing the long turnover time among the equipments, reducing the effective utilization rate of the equipments, at the same time increasing the production cost and the labor strength. The present invention makes a plurality of de-ironing tanks connect in series to form a multilevel continuous de-ironing system into which the copper cobalt solution containing iron is put continuously, the copper cobalt solution is performed with the oxidation treatment firstly to make ferrous iron in the solution to be oxidized completely into ferric iron, and then the copper cobalt solution carries out the multilevel continuous iron removal, and utilizes the pipeline port fall existing between the tanks to flow into the next tank from the last tank. Through adopting the present invention, the continuous input and output of the feed liquid is realized, the production continuity is good, the automatic control is realized completely, the labour force is reduced, the working intensity is lowered, and the production efficiency is high.

Description

technical field [0001] The invention relates to a method for removing iron from a copper-cobalt ore leaching solution, in particular to a method for continuously removing iron by oxidation of a copper-cobalt solution. Background technique [0002] The current iron removal method of copper-cobalt ore leaching solution adopts intermittent iron removal method. The so-called intermittent iron removal means that the iron-containing copper-cobalt solution completes a series of reaction processes such as oxidation and neutralization in a single iron removal tank. Finally, all the materials in the iron removal tank must be transferred out at one time before they can be fed into production again. The above-mentioned intermittent iron removal method cannot realize the continuous input and output of materials, resulting in a long turnaround time for materials between equipment, reducing the The effective utilization rate of equipment, the number of equipment used is large, but also inc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/44
CPCY02P10/20
Inventor 蒋航宇朱伟王伟东徐斌
Owner ZHEJIANG HUAYOU COBALT
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