Thixotropy high-strength gel diverting agent

A high-strength, diverting agent technology, applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve problems such as failure of operation measures, inability to meet design requirements, and degradation of gel performance

Active Publication Date: 2008-08-27
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] (1) During the migration of the solution in the large pores and hyperpermeable strips and the process of polymerizing and cross-linking to form a gel under formation conditions, it is very easy to be diluted under the action of reservoir formation water, and the dilution will cause the monomer solution system The change of the proportion of each reaction component leads to the failure of the monomer solution system to form a gel, or the performance of the formed gel is reduced, which cannot meet the design requirements, resulting in the failure or poor effect of the operation measures;
[0007] (2) Th...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Take the application at 80°C as an example.

[0028] Take (0.3% xanthan gum + 0.005% chromium acetate + 0.003% mixed solution of ammonium phosphate and ammonium dihydrogen phosphate) to form a thixotropic system, take (6% acrylamide + 0.05% N-N'methylenebisacrylamide + 0.004% ammonium persulfate) to form the monomer solution system, the thixotropic control system, the monomer solution system and the total water mass are 100%, and the two are mixed at room temperature to form a uniform, single-phase composite system with a viscosity of 35.0mPa·S. The strength is 0.01Pa.

[0029] After the composite system was placed at 80°C for 30 minutes, a cross-linking reaction between the components of the thixotropic control system occurred, forming a thixotropic weak gel, the viscosity increased to about 4500mPa·S, and the strength increased to 0.80Pa; at this time, the A system that forms a thixotropic weak gel is applied for 100s -1 The viscosity of the system decreases rapidly...

Embodiment 2

[0032] Take the application at 60°C as an example.

[0033] Take (0.3% xanthan gum + 0.01% chromium acetate + 0.01% mixed solution of ammonium phosphate and ammonium dihydrogen phosphate) to form a thixotropic system, take (6% acrylamide + 0.05% N-N'methylenebisacrylamide + 0.004% ammonium persulfate) to form a monomer solution system, the thixotropic control system, the monomer solution system and the total mass of water are 100%, and the two are mixed at 60°C to form a uniform, single-phase composite system with a viscosity of 35.0mPa·S , the strength is 0.01Pa.

[0034] After the composite system was placed at 60°C for 60 minutes, a cross-linking reaction between the components of the thixotropic control system occurred, forming a thixotropic weak gel, the viscosity increased to 5000mPa·S, and the strength increased to about 1.8Pa; at this time, the A system that forms a thixotropic weak gel is applied for 100s -1 The viscosity of the system decreases rapidly to 37.5mPa·S...

Embodiment 3

[0037] Take the application at 30°C as an example.

[0038] Take (0.3% xanthan gum + 0.02% chromium acetate + 0.05% mixed solution of ammonium phosphate and ammonium dihydrogen phosphate) to form a thixotropic system, take (6% acrylamide + 0.05% N-N'methylenebisacrylamide + 0.15% ammonium persulfate) to form the monomer solution system, the thixotropic control system, the monomer solution system and the total water mass are 100%, and the two are mixed at room temperature to form a uniform, single-phase composite system with a viscosity of 35.0mPa·S. The strength is 0.01Pa.

[0039] After the composite system was placed at 30°C for 60 minutes, a cross-linking reaction between the components of the thixotropic control system occurred, forming a thixotropic weak gel, the viscosity increased to 5000mPa·S, and the strength increased to 1.20Pa; at this time, the formation of The system of thixotropic weak gel is applied for 100s -1 The viscosity of the system decreases rapidly to ...

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Abstract

The invention relates to a thixotropy high-intensity gel diverting agent which is used for high water-cut oil field cracks and the plugging of extra-high permeable zone channeling path. The process for preparation comprise the following steps: adding xanthan gum (XC) 0.1%-1%, chromic acetate 0.001-0.1%, 0.025-0.5% thixotropic control system of mixed solution of ammonium phosphate and monoammonium phosphate in a nomer solution system which is formed by conventional acrylamide monomer, wherein the viscosity is 12.6-32.0MPa.S under the temperature scope which is 30-80 DEG C, and shearing speed which is 100s-1, wherein viscosity can rapidly backs up to 50-100 times in 30 min under low-shearing state in carks and big pore path, the intensity G' is 0.5-1Pa, effectively protecting plugging agent solution system from being diluted by water, guaranteeing the stability of each water soluble component ratio of the plugging agent system, and the final gelling time is 2-10 hours, which can be controlled, and the final intensity G' is 200-500 Pa.

Description

technical field [0001] The invention relates to a thixotropic high-strength gel-steering agent used for plugging channeling passages such as fractures in high water-cut oilfields and ultra-high permeability zones. Background technique [0002] Water injection development is a development method commonly used in my country's oilfields. At present, the annual water injection volume of the eastern oilfield alone is nearly 700 million m 3 , The cost of water injection is more than 4 billion yuan. However, the existence of a large number of fractures, high-permeability strips and other water-flow dominant channels in the reservoir leads to inefficient or ineffective circulation of injected water along the high-permeability dominant channels, causing problems such as high water cut in the oil field and a substantial increase in oil production costs, resulting in a huge waste of resources. [0003] It has become the main body and focus of the development work of old oilfields to i...

Claims

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Application Information

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IPC IPC(8): C09K8/76
Inventor 唐孝芬刘玉章熊春明刘戈辉魏发林覃和
Owner PETROCHINA CO LTD
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