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Additive for preparing fine oxide dispersion steel, preparation and use thereof

A technology of additives and oxides, applied in the field of metallurgy, can solve problems such as difficult mass production of molten steel

Inactive Publication Date: 2008-11-12
ANGANG STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in this document, it is also mentioned that molten steel with a high oxygen content is mixed with molten steel to which a deoxidizer is added, and it is difficult to mass-produce molten steel by this method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0067] Preparation of low melting point pre-melted slag, take CaO powder 40%, Al 2 o 3 Powder 35%, SiO 2 Powder 10%, MgO powder 10%, CaF 2 Put 5% of the powder into the mixer for uniform mixing, then melt and cool in the magnesia crucible, and then grind it into a powder with a particle size of 1nm-3.5mm, and its melting point is 1100-1550°C for later use; then follow the formula Proportioning: 30% of low-melting pre-melted slag powder, 5% of calcium fluoride powder, 55% of calcium oxide powder, 5% of calcium carbonate, and 5% of clay with a particle size of 1nm to 3.5mm are put into the mixer for mixing. Mix the materials uniformly for 1-8 hours, wherein the activity of the calcium oxide is ≥200ml; put the prepared powder into a drying equipment at 80-200°C for 8-24 hours; The carbon steel strip is used as the sheath of the cored wire, and the wire core is the above-mentioned powder that has been dried. On the wire making machine, the single-layer steel strip is lapped to ...

Embodiment 2

[0071] Take CaO10% and Al according to the formula ratio 2 o 3 50%, SiO 2 5%, MgO5%, CaF 2 30% The method for preparing low-melting point pre-melted slag powder is the same as that in Example 1; take 1% of low-melting point pre-melted slag powder, 30% of calcium fluoride, 40% of magnesium carbonate, and 29% of magnesium oxide with a particle size of 1nm to 3.5mm. . Its powder preparation process and drying treatment are the same as in Example 1; the low-carbon steel strip with a thickness of 2 to 5 mm is used as the sheath of the cored wire, and the wire core is the dried above-mentioned powder on the wire making machine, and the packaging adopts a single Core-spun wire is produced by overlapping steel strips, the wire-wrapping speed is 8-30m / min, and the powder content of the core-spun wire is 100-240g / m. Core-spun wire is packaged in 1000-2000m / roll, which is beneficial to directly control the amount and speed of addition. The cross-section of the core-spun wire is circu...

Embodiment 3

[0075] Take CaO70% and Al according to the formula ratio 2 o 3 15%, SiO 2 3%, MgO 2%, CaF 2 10% method for preparing low-melting point pre-melted slag powder is the same as in Example 1; the particle size is 1nm to 3.5mm, and the prepared low-melting point pre-melted slag powder is 45% mixture of calcium carbonate and magnesium carbonate, 30% of calcium oxide and magnesium oxide. 10% of the mixture, 10% of bentonite, and 5% of water glass powder are placed in a vertical mixer and mixed for 2 to 8 hours; then dried on the drying equipment, the drying temperature is 80 to 200 ° C, and the time is 8 to 8 hours. 24h is the finished powder. Cool to room temperature and put it into an ultra-thin high-strength polyethylene plastic bag, and pack it in a moisture-proof sealed package of 1000kg / bag. The package must be well sealed to prevent moisture, and it should be used within 20 days.

[0076] The technical method for preparing fine oxide dispersion steel comprises the following...

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Abstract

The invention relates to an external furnace refining technology for steelmaking, in particular to an additive for preparing fine oxide dispersion steel, a method for making the same and an application of the additive. The invention belongs to the metallurgical technology field. The additive consists of raw materials proportioned according to a formula; low-melting point pre-smelting slag powder, calcium fluoride, calcium carbonate, magnesium carbonate or a mixture of calcium carbonate and magnesium carbonate, calcium oxide, magnesia or a mixture of calcium oxide and magnesia and caking agent are respectively adopted and prepared to additives with various additive types of core-spun yarn, powder, a composite pellet and a composite sphere; through adopting wire feeding, powder spraying and pill shooting, or even a direct throwing mode, the additive is fed in LF, RH, VD or CAS-OB in order that the oxide class impurity is fine, dispersed and distributed in steel; and the addition type is beneficial for application and can stably and rapidly produce the fine oxide dispersion steel with an oxide grain diameter of less than 1mu m in large quantities, thereby greatly improving the quality of rolled steel and reducing the smelting cost.

Description

technical field [0001] The invention relates to an out-of-furnace refining technology for steelmaking, in particular to an additive for preparing fine oxide-dispersed steel, its preparation method and application, and belongs to the technical field of metallurgy. Background technique [0002] It is well known that the beneficial inclusions (CaO, Ti 2 o 3 , BN, REM (O, S), VN, TiN, ZrO 2 etc.) can improve the quality of molten steel. In recent years, inclusions with a particle size of less than 2 μm, especially the technology of improving the dispersion amount in steel by using oxide-based inclusions has attracted attention. Some recent patents disclose that in order to increase the dispersion of oxides, during pre-deoxidation, adjust the oxygen content to a certain range, and then add a strong deoxidizer, which is a method of using the primary deoxidation product. [0003] For example, in the patent JP 2001-288509 document, after the oxygen in molten steel is controlled ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C7/04
CPCY02P10/134
Inventor 唐复平王晓峰刘万山孟劲松任子平李德刚陈本文王仁贵张军王文仲李镇张晓军孙群栗红常桂华
Owner ANGANG STEEL CO LTD