Phosphor, fluorescent lamp using the same, and display device and illuminating device using fluorescent lamp
A technology of phosphors and fluorescent lamps, applied in the field of yttrium vanadate, which can solve the problems of reducing brightness and achieve the effects of improving brightness, wide color gamut, color reproducibility and brightness
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[0074] Phosphors were synthesized according to the following steps: Weighing a predetermined amount of Y used as a raw material 2 o 3 , V 2 o 5 、Eu 2 o 3 , Tb 4 o 7 and Sm 2 o 3 , and mixed it in ethanol by a ball mill system. The resulting mixture was filtered, dried, placed in a quartz crucible, and then calcined at 1100° C. in air for 2 hours. After calcination, the mixture is rinsed with alkaline solution and water and dried.
[0075] Thus, phosphor YVO doped with 10ppm to 5000ppm of Tb was synthesized. 4 : Phosphor YVO doped with Eu and Sm from 50ppm to 25000ppm 4 :Eu. As a comparative example, phosphor YVO without doping Tb or Sm was synthesized 4 :Eu.
[0076] figure 1 is shown that in the example of the present invention, Tb-doped YVO 4 : Comparison diagram of the results of the correlation between brightness and intensity of excitation light irradiation between Eu and common phosphors;
[0077] figure 1 is shown by irradiating Y with 254 nm UV light ...
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[0117] To improve YVO 4 : The brightness saturation phenomenon of Eu and increase its brightness, adding a small amount of Tb or Sm to YVO 4 : Eu.
[0118]
[0119] figure 2 It is shown that in the example of the present invention, the preparation of YVO for the synthesis of doped Tb 4 : Table of raw materials of Eu.
[0120] Figure 8 is to show that in the example of the present invention, the preparation for the synthesis of YVO doped with Sm 4 : Table of raw materials of Eu.
[0121] Such as figure 2 and Figure 8 shown, using Y 2 o 3 (purity 99.9%), V 2 o 5 (purity 99.99%) and Eu 2 o 3 (purity 99.9%) as a synthetic raw material. For Tb and Sm to be added, use Tb 4 o 7 (purity 99.99%) and Sm 2 o 3 (purity 99.9%) as raw material.
[0122] according to figure 2 and Figure 8 These materials were mixed in the indicated mixing amounts. In addition, as a comparative example, a sample not doped with Tb or Sm was prepared. Add V at a stoichiometric rat...
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