Molecular engram material selectively removing TSNA in cigarette flue gas, preparation and application method thereof
A molecular imprinting, cigarette smoke technology, applied in application, tobacco, tobacco processing, etc., can solve problems such as inability to directly use cigarette tip sticks, time-consuming, labor-intensive, inefficient, and imprinting site destruction effects, and achieve excellent selectivity High adsorption performance, high utilization rate, and little effect on cigarette smoking
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Embodiment 1
[0034] 1. Preparation of Additives
[0035] (1) Activation and silanization of silica gel: reflux with 10% hydrochloric acid by volume fraction for 12 hours, wash with distilled water until ph = 7.0, and then vacuum dry for later use; put 5g of activated silica gel and 50ml of toluene into a round bottom flask, add 2ml 3-aminopropyltriethoxysilane, 1ml triethylamine, heated to reflux for 24 hours, filtered the reacted silica gel, washed with methanol and chloroform, and dried in vacuum.
[0036] (2) Preparation of Silica Surface Imprinted Polymers (MIPs) and Non-Molecularly Imprinted Polymers (NMIPs)
[0037] Take 1mmol of 3-pyridinemethanol (template molecule) and dissolve it in 10mL of methanol and 30mL of chloroform, add 4mmol of functional monomer 4-vinylpyridine, 4g of silanized silica gel, and shake in a constant temperature oscillator for 3h to make the template molecule and the functional monomer Mix the body and silica gel thoroughly, then add 15mmol crosslinking age...
Embodiment 2
[0042] 1. Preparation of Additives
[0043] (1) Activation and silanization of silica gel: reflux with 10% hydrochloric acid by volume fraction for 12 hours, wash with distilled water until ph=7.0, and then vacuum dry for later use; put 10 g of activated silica gel and 100 ml of toluene into a round-bottomed flask, add 393 - Aminopropyltriethoxysilane, 1ml of pyridine, heated to reflux for 24 hours, filtered the reacted silica gel, washed with methanol and chloroform, and dried in vacuum.
[0044] (2) Preparation of Silica Imprinted Polymers (MIPs) and Non-Molecularly Imprinted Polymers (NMIPs)
[0045] Dissolve 0.25mmol of nicotinamide (template molecule) in 60mL of chloroform, add 1.25mmol of functional monomer methacrylic acid (MAA), 4g of silanized silica gel, place in a constant temperature oscillator and shake for 3h, so that the template molecule and functional monomer and Mix the silica gel well, then add 5mmol crosslinking agent ethylene glycol dimethacrylate (EDMA) ...
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