The application relates to the technical field of
ammonium oxidation, and discloses an
anode material for
ammonium oxidation under a low-concentration
chloride ion condition and a preparation method thereof.The
anode material takes
manganese dioxide as a carrier and is loaded with monatomic silver, and the loading amount of the monatomic silver is less than 0.1 wt%.In the preparation process, first,
constant current density electrodeposition is carried out to prepare a MnO2 /
platinum-coated
titanium mesh; then, a wet chemical immersion method is used to load Ag on the MnO2 substrate; finally, high-temperature
air atmosphere calcination is carried out to prepare a monatomic Ag / MnO2
anode material.The application utilizes the
acid resistance of MnO2 itself and the strong
metal carrier interaction between
metal Ag and MnO2 to realize stable and continuous
electrolysis operation; and Ag and MnO2 realize the enrichment of low-concentration
chloride ions at the anode interface through
chemical affinity and physical adsorption, thereby realizing the efficient generation of active
chlorine under the condition of low-concentration
chloride ions.