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Double-temperature dyeing method of chloro-s-triazine and vinyl sulfone double-active group active dye

A technology of reactive dyes and dual reactive groups, which is applied in the field of reactive dye exhaust dyeing, can solve the problems of incomplete dye reaction, low dyeing temperature, and affecting the dyeing fixation rate of dyes, so as to be beneficial to environmental protection, reduce floating color, and reduce The effect of the amount of alkali agent

Inactive Publication Date: 2009-04-22
ZHEJIANG SCI-TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the addition of alkali and the dyeing temperature have dual characteristics. If the alkali is too weak and the dyeing temperature is too low, the dye reaction will not be complete, which will affect the dyeing fixation rate of the dye; if the alkali is too strong and the dyeing temperature is too high, the dye will be hydrolyzed and become invalid, which will also affect the dye. dye fixation rate

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Embodiment 1: light color (0.01% of dyestuff consumption) dyeing:

[0042] (1) Dyeing formula:

[0043] Dosage of M-type reactive dyes (to fabric weight) 0.01%

[0044] Yuanming powder 10g / L

[0045] Soda ash 2g / L

[0046] Bath ratio 1:15

[0047] (2) Dyeing process:

[0048] At room temperature, add water, run the fabric, add sodium bicarbonate, add enough water—30min to heat up to 60°C—keep warm for 30min, add 1 / 5 soda ash—keep warm for 10min, add the rest of soda ash—keep warm for 20min, and then Raise the temperature to 85°C——after keeping warm for 20 minutes, wash with water, boil with soap, and wash with water.

[0049] (3) Process description:

[0050]In the dyeing process, the addition of sodium sulfate acts as a dyeing accelerator, improving the dyeing and fixation rate of the dye. However, if the dosage is too high, it is easy to cause color and flower phenomenon, so the light color is generally about 10-20g / L. The addition of soda ash is conducive to ...

Embodiment 2

[0051] Embodiment 2: moderate depth (2% of dye consumption) dyeing:

[0052] (1) Dyeing formula:

[0053] B-type reactive dye dosage (to yarn weight) 2%

[0054] Yuanming powder 40g / L

[0055] Soda ash 18g / L

[0056] Bath ratio 1:10

[0057] (2) Dyeing process:

[0058] At room temperature, add water, run the yarn, add Yuanming powder, add enough water—30min to heat up to 60°C—keep warm for 30min, add 1 / 4 soda ash—keep warm for 10min, add the rest of soda ash—keep warm for 25min, Then heat up to 90°C——after keeping warm for 20 minutes, wash with water, boil with soap, and wash with water.

[0059] (3) Process description:

[0060] In the dyeing process, the addition of sodium sulfate acts as a dyeing accelerator, improving the dyeing and fixation rate of the dye. However, if the dosage is too high, it is easy to cause color and flower phenomenon, and the medium depth is generally about 30-50g / L. The addition of soda ash is conducive to the combination of dyes and fiber...

Embodiment 3

[0061] Embodiment 3: deep color (5.0% of dyestuff consumption) dyeing:

[0062] (1) Dyeing formula:

[0063] B-type reactive dye dosage (to fabric weight) 5%

[0064] Salt 70g / L

[0065] Soda ash 25g / L

[0066] Bath ratio 1:8

[0067] (2) Dyeing process:

[0068] At room temperature, add water, run the fabric, add salt, add enough water——30 minutes to heat up to 65°C——after holding for 30 minutes, add 1 / 5 of soda ash——hold for 10 minutes, add the remaining soda——hold for 30 minutes, and then heat up to 90°C——After keeping warm for 20 minutes, wash with water, boil with soap, and wash with water.

[0069] (3) Process description:

[0070] The addition of salt in the dyeing process also plays a role in promoting dyeing and improving the dyeing and fixation rate of dyes. Therefore, the dark color is generally about 70-80g / L. The addition of soda ash is conducive to the combination of dyes and fibers, but the presence of alkali will also cause the dyes to hydrolyze and bec...

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PUM

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Abstract

The invention discloses a double temperature dyeing method for a reactive dye with double active groups of monochlorotriazine and vinyl sulfone. The formulas of the double temperature dyeing method are as follows respectively: 0.01 to 10 percent of M or B type reactive dye (the weight relative to that of fabrics or yarns), 10 to 100g / L of glauber salt or common salt, and 2 to 30g / L of calcined soda, wherein the bath ratio is between 1 to 6 and 1 to 15; or 0.01 to 10 percent of M or B type reactive dye, 10 to 100g / L of glauber salt or common salt, and 2 to 4g / L of base substituent 310-F, wherein the bath ratio is between 1 to 6 and 1 to 15; or 0.01 to 10 percent of M or B type reactive dye, 10 to 100g / L of glauber salt or common salt, 1 to 2g / L of base stabilizer 310, and 0.8 to 2g / L of sodium hudroxide, wherein the bath ratio is between 1 to 6 and 1 to 15. The dying process is as follows: cotton, hemp or an adhesive fabric, double temperature dyeing, soaping, and finishing. The utilization rate of the dye is improved by between 2 and 5 percent; the using amount of an alkaline agent can save 20 to 30 percent; and after the dyeing, the stage temperature is increased, the desorption rate of the hydrolised dye is increased, the loose color on fiber is reduced, and the water scrubbing is reduced after the soaping. The method reduces the drainage of sewage, and is favorable to the environmental protection.

Description

technical field [0001] The invention relates to a method for exhaust dyeing of reactive dyes, in particular to a method for dual-temperature dyeing of reactive dyes with dual active groups of monochloro-s-triazine and vinyl sulfone. Background technique [0002] Reactive dyes are a relatively new class of dyes, which have the advantages of bright color, excellent color fastness, and convenient dyeing. At present, it is widely used in the dyeing of cotton, hemp, silk, wool and other fibers. The molecular structure of reactive dyes contains active groups, and the dyes and fibers undergo chemical reactions to combine under alkaline and certain dyeing temperature conditions. However, the addition of alkali and the dyeing temperature have dual characteristics. If the alkali is too weak and the dyeing temperature is too low, the dye reaction will not be complete, which will affect the dyeing fixation rate of the dye; if the alkali is too strong and the dyeing temperature is too h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P3/66D06P1/382D06P1/384
Inventor 王光明陈君莉周秋宝
Owner ZHEJIANG SCI-TECH UNIV
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