Laser marked plastic and preparation method thereof

A laser marking and plastic technology, which is applied in the field of markable plastics and their preparation, can solve the problems of a large amount of additives added, a decrease in the physical properties of materials, and a large increase in cost, and achieves the effect of broad application prospects and simple and reliable processes.

Active Publication Date: 2009-04-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] However, it is known that the additives currently used for laser marking have certain disadvantages. They make dark markings on a light background lack sufficient contrast, that is, sharpness; or the markings have blurred lines and low sharp angles; If the amount is too much, the physical properties of the material will decrease, such as the impact performance, etc.; and the cost will increase more due to the addition of a large amount.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~3

[0040] For polyethylene resin: mix polyethylene resin (low-density polyethylene, LDPE, brand 1F7B, Sinopec Beijing Yanhua Petroleum Co., Ltd.) and simethicone oil (brand 201, viscosity is 1000 centipoise, Beijing Chemical Plant No. 2) Place in a blender and mix evenly; then the treated LDPE, superfine fully vulcanized powdered styrene-butadiene rubber (brand VP 101, Beijing Beihuayan Chemical New Technology Co., Ltd., average particle diameter 100nm, gel content 90.0%), pearlescent Pigment (brand LS825, its main components are: the mica base is mainly covered with antimony trioxide, produced by Merck, Germany), antioxidant 1076 (Beijing Chemical Factory No. 3) and antioxidant DSTP (Beijing Chemical No. 3 Factory) and stir evenly Finally, the mixture was added to a twin-screw extruder (Germany WP Company, model ZSK-25) for melt blending and extruding, and then granulated. The extrusion temperature was 130-190° C., and the screw speed was 300 rpm. Dry the extruded pellets in an ...

Embodiment 4~6

[0047] For polypropylene resin (PP): Polypropylene resin (PP, brand K9015, produced by Sinopec Yangzi Petrochemical Company) and simethicone oil (brand 201, viscosity 1000 centipoise, Beijing Chemical Industry No. Mix homogeneously in mixer; Then after the PP after processing, superfine fully vulcanized powder styrene-butadiene rubber (same as embodiment 1), pearlescent pigment (same as embodiment 1) are mixed homogeneously, compounding material is added twin-screw extruder ( Germany WP company, model is ZSK-25) in the melt blending extruded rear granulation, extrusion temperature is 190~230 ℃, screw speed 300rpm. Dry the extruded pellets in an oven at 80°C for 6 hours, and then inject them into standard strips at a temperature of 190-230°C for laser marking tests and related performance tests. The specific formula and properties are shown in Table 2.

Embodiment 7~10

[0053] For polystyrene: polystyrene (PS, grade 666D, Sinopec Beijing Yanhua Petroleum Co., Ltd.) and simethicone oil (grade 201, viscosity of 1000 centipoise, Beijing Chemical Plant No. 2) were placed in a mixer for Mix homogeneously; Then after PS after processing, superfine fully vulcanized powder styrene-butadiene rubber (same as embodiment 1), pearlescent pigment (same as embodiment 1) are stirred, compound is added twin-screw extruder (Germany WP company , the model is ZSK-25) in the melt blending extrusion and pelletizing. The temperature in the heating section of the extruder is 189-202-210-210-210-205°C, and the speed of the main machine is 350rpm; the obtained pellets are dried at 80°C for 5 hours, injected at 200°C, and prepared as required. , to test the mechanical and optical properties. Its formulation and properties are shown in Table 3.

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Abstract

The invention relates to plastic which can be marked by laser, which comprises the following blended components in weight portion: 100 portions of plastic, 0.1 to 10 portions of powder rubber with the average grain diameter of between 50 and 200 nanometers and the gel content of over 60 weight percent, and 0.01 to 5 portions of pearlescent pigment or metallic oxide. The invention also relates to a method for preparing the plastic which can be marked by the laser. The preparation method comprises the steps of melting and blending the components comprising the plastic, the powder rubber and the pearlescent pigment to prepare the plastic which can be marked by the laser. The plastic which can be marked by the laser can obtain a laser mark with higher contrast grade under the action of the laser. The preparation method has the advantages of simple and reliable processes.

Description

technical field [0001] The invention relates to a markable plastic and a preparation method thereof, in particular to a laser-markable thermoplastic and a preparation method thereof. Background technique [0002] Labeling on produced items is becoming increasingly important in almost all industrial sectors. For example, it is often necessary to indicate the production date, expiration date, barcode, company's trademark, serial number, etc. on the item. [0003] At present, there are many technical methods for printing marks on objects, such as screen printing and transfer printing, embossing, embossing, ink printing, etc. are all well-known printing technologies. These printing methods are surface printing, which means that the resulting identification mark becomes difficult to read due to mechanical damage, friction, chemical action and the like, and this printing method is difficult to apply to curved or textured surfaces, Furthermore, the special processing costs requir...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/00C08L27/06C08L25/06C08L33/12C08L75/04C08L53/02C08L77/00C08L67/00C08L59/00C08K9/02G09F19/12C08L9/00C08L83/04C08K3/22
Inventor 张师军王小兰张薇张丽英吕明福尹华邵静波张浩李魁吕芸陈力刘涛
Owner CHINA PETROLEUM & CHEM CORP
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