Laser marked plastic and preparation method thereof
A laser marking and plastic technology, which is applied in the field of markable plastics and their preparation, can solve the problems of a large amount of additives added, a decrease in the physical properties of materials, and a large increase in cost, and achieves the effect of broad application prospects and simple and reliable processes.
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Embodiment 1~3
[0040] For polyethylene resin: mix polyethylene resin (low-density polyethylene, LDPE, brand 1F7B, Sinopec Beijing Yanhua Petroleum Co., Ltd.) and simethicone oil (brand 201, viscosity is 1000 centipoise, Beijing Chemical Plant No. 2) Place in a blender and mix evenly; then the treated LDPE, superfine fully vulcanized powdered styrene-butadiene rubber (brand VP 101, Beijing Beihuayan Chemical New Technology Co., Ltd., average particle diameter 100nm, gel content 90.0%), pearlescent Pigment (brand LS825, its main components are: the mica base is mainly covered with antimony trioxide, produced by Merck, Germany), antioxidant 1076 (Beijing Chemical Factory No. 3) and antioxidant DSTP (Beijing Chemical No. 3 Factory) and stir evenly Finally, the mixture was added to a twin-screw extruder (Germany WP Company, model ZSK-25) for melt blending and extruding, and then granulated. The extrusion temperature was 130-190° C., and the screw speed was 300 rpm. Dry the extruded pellets in an ...
Embodiment 4~6
[0047] For polypropylene resin (PP): Polypropylene resin (PP, brand K9015, produced by Sinopec Yangzi Petrochemical Company) and simethicone oil (brand 201, viscosity 1000 centipoise, Beijing Chemical Industry No. Mix homogeneously in mixer; Then after the PP after processing, superfine fully vulcanized powder styrene-butadiene rubber (same as embodiment 1), pearlescent pigment (same as embodiment 1) are mixed homogeneously, compounding material is added twin-screw extruder ( Germany WP company, model is ZSK-25) in the melt blending extruded rear granulation, extrusion temperature is 190~230 ℃, screw speed 300rpm. Dry the extruded pellets in an oven at 80°C for 6 hours, and then inject them into standard strips at a temperature of 190-230°C for laser marking tests and related performance tests. The specific formula and properties are shown in Table 2.
Embodiment 7~10
[0053] For polystyrene: polystyrene (PS, grade 666D, Sinopec Beijing Yanhua Petroleum Co., Ltd.) and simethicone oil (grade 201, viscosity of 1000 centipoise, Beijing Chemical Plant No. 2) were placed in a mixer for Mix homogeneously; Then after PS after processing, superfine fully vulcanized powder styrene-butadiene rubber (same as embodiment 1), pearlescent pigment (same as embodiment 1) are stirred, compound is added twin-screw extruder (Germany WP company , the model is ZSK-25) in the melt blending extrusion and pelletizing. The temperature in the heating section of the extruder is 189-202-210-210-210-205°C, and the speed of the main machine is 350rpm; the obtained pellets are dried at 80°C for 5 hours, injected at 200°C, and prepared as required. , to test the mechanical and optical properties. Its formulation and properties are shown in Table 3.
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