Negative type infrared light responsive composition, negative type printing plate and method of use thereof
A composition, infrared light technology, applied in the field of printing plates, to achieve the effects of high print resistance, good lipophilicity and high sensitivity
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Embodiment 1
[0036] (1) Preparation of infrared light-sensitive composition
[0037] (a) Synthesis of hydrophilic polymer I: Add 500ml of absolute ethanol into a 1L four-necked round bottom flask equipped with a sealed mechanical stirring device, reflux condenser, dropping funnel and nitrogen introduction tube, start stirring, and pass in Dry nitrogen and bubble for 15 minutes. Heat the water bath to 60℃, after the temperature is constant, drop in a solution consisting of 144g acrylic acid (2mol), 142g acrylamide (2mol), 1g benzoyl peroxide and 200ml absolute ethanol from which the polymerization inhibitor has been removed, for 30 minutes Finish dripping. After maintaining the reaction at 60°C for 5 hours, add 1 g of benzoyl peroxide, maintain the temperature, continue the reaction for 10 hours, and then terminate the reaction. The reaction mixture was naturally cooled to room temperature.
[0038] The cooled reaction liquid was dropped into 5 L of acetone with a strong stirring and dispersi...
Embodiment 2
[0059] (1) Preparation of infrared light-sensitive composition
[0060] (a) Synthesis of hydrophilic polymer II: Add 500ml of absolute ethanol into a 1L four-necked round bottom flask equipped with a sealed mechanical stirring device, reflux condenser, dropping funnel and nitrogen introduction tube, start stirring, and pass in Dry nitrogen and bubble for 15 minutes. Heat the water bath to 60℃, after the temperature is constant, drop in a solution consisting of 129g methacrylic acid (1.5mol), 213g acrylamide (3mol), 1g benzoyl peroxide and 300ml absolute ethanol from which the inhibitor has been removed , 30 minutes to finish. After maintaining the reaction at 60°C for 5 hours, add 1 g of benzoyl peroxide, maintain the temperature, continue the reaction for 10 hours, and then terminate the reaction. The reaction mixture was naturally cooled to room temperature.
[0061] The cooled reaction liquid was dropped into 5 L of acetone with a strong stirring and dispersing device to prec...
Embodiment 3
[0082] (1) Preparation of infrared light-sensitive composition
[0083] (a) Synthesis of hydrophilic polymer III: Add 500ml of absolute ethanol into a 1L four-necked round bottom flask equipped with a sealed mechanical stirring device, reflux condenser, dropping funnel and nitrogen introduction tube, start stirring, and pass in Dry nitrogen and bubble for 15 minutes. Heat the water bath to 60°C. After the temperature becomes constant, drop a solution consisting of 172g methyl acrylate (2mol), 213g acrylamide (3mol), 1g benzoyl peroxide and 300ml absolute ethanol from which the polymerization inhibitor has been removed. Finished in 30 minutes. After maintaining the reaction at 60°C for 5 hours, add 1 g of benzoyl peroxide, maintain the temperature, and continue the reaction for 10 hours before stopping the reaction. The reaction mixture was naturally cooled to room temperature.
[0084] The cooled reaction liquid was dropped into 5L of acetone with a strong stirring and dispersin...
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