Silicone rubber composition for coating of woven fabric, and coated woven fabric
A silicone rubber composition, a silicone rubber coating technology, applied in the directions of fabrics, textiles, textiles, and papermaking, etc., can solve the problems of not teaching fabric coating compositions and the like
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[0048] The present invention is further described with reference to Examples, wherein all parts are parts by mass and all viscosities are measured at 25°C. In the examples, Me represents methyl and Vi represents vinyl.
[0049] [Measurement method of physical properties of silicone rubber]
[0050] A cured silicone rubber sample with a thickness of 2 mm was prepared by pressure-curing the silicone rubber composition at 150° C. under a pressure of 20 MPa for 5 minutes. The hardness of the silicone rubber is measured using a type A durometer according to JIS K6253. Tensile strength, elongation, and tear strength are measured in accordance with JIS K6251 and JIS K6252. In addition, the stress generated at 100% elongation was measured as 100% modulus according to JIS K6251.
[0051] [Measurement method of bond strength]
[0052] A nylon 66 fabric with a warp density of 46 threads / inch and a weft thread density of 46 threads / inch is coated with a 1mm thick silicone rubber compo...
manufacture example 1
[0058] Fill the Ross mixer with the following components: 100 parts by mass of dimethylpolysiloxane (which corresponds to the Component (a-1)); 60 parts by mass of wet-process silica (Nipsil LP; product of Nippon Silica Co., Ltd.); 9.7 parts by mass of hexamethyldisilazane; 4.4 parts by mass of water and 0.7 mass parts of a copolymer of methyl vinyl siloxane and dimethyl siloxane (10.9 mass % ethylene base content; corresponding to component (a-6) in Table 1). After these components were uniformly mixed at room temperature, the resulting mixture was heat-treated at 200° C. for 2 hours under reduced pressure, whereby a flowable silica master batch 1 was prepared.
manufacture example 2
[0060] The Ross mixer was filled with the following components: 100 parts by mass of dimethylpolysiloxane whose molecular ends were terminated with dimethylvinylsiloxy groups and whose viscosity was 40,000 mPa·s; 40 parts by mass of BET specific surface area 225m 2 / g of fumed silica; 7 parts by mass of hexamethyldisilazane; 2 parts by mass of water; and 0.2 parts by mass of molecular ends capped with dimethylhydroxysiloxy groups and a viscosity of 20mPa. s A copolymer of methylvinylsiloxane and dimethylsiloxane (vinyl content of 10.9% by mass; corresponding to component (a-6) in Table 1). After mixing these components at room temperature to make them uniform, the resulting mixture was heat-treated at 200° C. for 2 hours under reduced pressure, whereby a flowable silica master batch 2 was prepared.
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